[Mn6O2[O2C-3,5-(NO2)2-C6H3]10-(C5H5N)2[(CH3)2CO]2].2(CH3)2CO.- 2(C2H5)2O and [Mn6O2(O2CC6H5)10-(NCCH3)4].
The structures of di(acetone)tetrakis(mu 3,5-dinitrobenzoato-kappa 2 O:kappa O')hexakis(mu-3,5-dinitrobenzoato-kappa O:kappa O')-di-mu 4-oxo-di(pyridine)tetramanganese(II)dimanganese (III)-acetone-diethyl ether (1/2/2), (1), and tetrakis(acetonitrile)tetrakis(mu 3-benzoato-kappa 2 O:kappa O')hexakis(mu-benzoato-kappa O:kappa O')-di-mu 4-oxo-tetramanganese(II)dimanganese(III), (2), are reported. Both compounds contain six octahedrally coordinated Mn centres, arranged as two MnII2MnIII2 (mu 4-O) tetrahedra sharing the MnIII-MnIII edge.
Halcrow
M A
MA
Department of Chemistry, Indiana University, Bloomington 47405-4001, USA.
Streib
W E
WE
Folting
K
K
Christou
G
G
D018360:Crystallography, X-Ray; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*
D009942:Organometallic Compounds; C096574:di(acetone)tetrakis(mu(3)-3,5-dinitrobenzoato-kappa(2)O-kappaO')hexakis(mu-3,5-dinitrobenzoato-kappaO-kappaO')-di-mu(4)-oxo-di-(pyridine)tetramanganese(II)dimanganese(III)-acetone-diethyl ether; C096575:tetrakis(acetonitrile)tetrakis(mu(3)-benzoato-kappa(2)O-kappaO')hexakis(mu-benzoato-kappaO-kappaO')-di-mu(4)-oxo-tetramanganese(II)dimanganese(III)