title: Heterobifunctional poly(ethylene oxide): synthesis of alpha-methoxy-omega-amino and alpha-hydroxy-omega-amino PEOs with the same molecular weights.
abstract: Well-defined alpha-methoxy-omega-amino and a alpha-hydroxy-omega-amino poly(ethylene oxide)s (PEOs) were obtained after chemical modifications of alpha-hydroxy-omega-allyl PEO which was synthesized by anionic polymerization of ethylene oxide (EO) with allyl alcoholate as initiator; molecular weights of the prepolymer were controlled by the monomer/initiator ratio. Addition of methyl iodide on the hydroxy function of this prepolymer led to an alpha-methoxy-omega-allyl PEO; completion of the reaction and purity of the resulting polymer were demonstrated by 1H, 13C NMR and GPC studies. Addition reactions of 2-amino-ethanethiol hydrochloride on alpha-hydroxy-omega-allyl PEO and alpha-methoxy-omega-allyl PEO in the presence of azobisisobutyronitrile (AIBN) led to the expected homopolymers without any side reactions as shown by 1H and 13C NMR spectra.
authors.affiliation: Department of Materials Science and Technology, Science University of Tokyo, Chiba, Japan.
authors.forename: S
authors.initials: S
authors.lastname: Cammas
authors.forename: Y
authors.initials: Y
authors.lastname: Nagasaki
authors.forename: K
authors.initials: K
authors.lastname: Kataoka
mesh_terms: D009682:Magnetic Resonance Spectroscopy; D008823:Micelles; D008970:Molecular Weight; D011092:Polyethylene Glycols / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D008823:Micelles; D011092:Polyethylene Glycols