Azidotetrakis(trimethylphosphine)nickel(II) tetrafluoroborate.
The title complex, [Ni(N3)(C3H9P)4]BF4, is a nearly perfect trigonal bipyramid with the azide group at an apical position. The metal-azide bond angle, Ni1--N1--N2, of 138.6(5) degrees is the largest observed for a terminal azide ligand.
Carson
C C
CC
Department of Chemistry, College of William and Mary, Williamsburg, Virginia 23187, USA.
Pike
R D
RD
Carpenter
G B
GB
D018360:Crystallography, X-Ray; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*
D009942:Organometallic Compounds; C094660:azidotetrakis(trimethylphosphine)nickel(II)