Linalool and cineole type glucosides from Cunila spicata.
The leaves of Cunila spicata yielded a monoterpenetriol and six glycosidic terpenoids derived from linalool, hydroxylated linalool and 1,8-cineole: 3,7-dimethyl-oct-1-ene-3,6,7-triol, linalool-O-beta-D-glucopyranoside, 3,7 dimethyl-octa-1,6-diene-3,8-diol-3-O-beta-D-glucopyranoside as well as 3,7-dimethyl-octa-1,5-diene-3,7-diol-3-O-beta-D-glucopyranoside, 3,7-dimethyl-octa-1,7-diene-3,6-diol-7-O-beta-D-glucopyranoside, 3,7- dimethyl-oct-1-ene-3,6,7-triol-6-O-beta-D-glucopyranoside and (1S,4R,6R)-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-O-beta- glucopyranoside. The structures of the glucosides were established by chemical and spectroscopic methods especially high field NMR techniques.
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Pharmazeutisches Institut, Universität Bonn, Federal Republic of Germany.
D000080462:Acyclic Monoterpenes; D001938:Brazil; D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D003511:Cyclohexanols; D000077591:Eucalyptol; D005960:Glucosides / Q000737:chemistry* / Q000302:isolation & purification; D009682:Magnetic Resonance Spectroscopy; D008610:Menthol / Q000031:analogs & derivatives* / Q000737:chemistry / Q000302:isolation & purification; D008958:Models, Molecular; D008969:Molecular Sequence Data; D015394:Molecular Structure; D039821:Monoterpenes; D018515:Plant Leaves; D010946:Plants, Medicinal; D013329:Structure-Activity Relationship; D013729:Terpenes / Q000737:chemistry* / Q000302:isolation & purification
D000080462:Acyclic Monoterpenes; D003511:Cyclohexanols; D005960:Glucosides; D039821:Monoterpenes; D013729:Terpenes; D008610:Menthol; C018584:linalool; D000077591:Eucalyptol