Tris(3,5-dimethylpyrazol-1-yl)methylsilane.
The structure consists of discrete molecules of tris-(3,5-dimethylpyrazol-1-yl)methylsilane, C16H24N6Si, that exhibit distorted tetrahedral SiN(pyrazole)3C geometry about the Si atom. The Si and methyl C atoms lie on threefold axes. The C--Si--N and N--Si--N bond angles are 111.3 (2) and 107.5 (2) degrees, respectively, while the Si--N bond length is 1.745 (5) A. The present work provides the first reported structure containing an Si--N(pyrazole) linkage.
Vepachedu
S
S
Department of Chemistry, Rutgers, State University of New Jersey, New Brunswick 08903, USA.
Stibrany
R T
RT
Knapp
S
S
Potenza
J A
JA
Schugar
H J
HJ
D003461:Crystallography; D015394:Molecular Structure; D011720:Pyrazoles / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*
D011720:Pyrazoles; D012821:Silanes; C093470:tris(3,5-dimethylpyrazol-1-yl)methylsilane