The reaction between epichlorohydrin and polysaccharides: Part 2, Synthesis of some model substances, with cyclic substituents.
Eight derivatives of methyl alpha-D-glucopyranoside, in which the substituents are part of cyclic structures, have been prepared as model substances for possible structural elements formed on reaction of polysaccharides with epichlorohydrin. The substances were converted into the permethylated alditol-1-d acetates and characterised by CIMS and EIMS.
Holmberg
L
L
Pharmacia LKB Biotechnology AB, Uppsala, Sweden.
Lindberg
B
B
Lindqvist
B
B
D004811:Epichlorohydrin / Q000737:chemistry*; D008401:Gas Chromatography-Mass Spectrometry; D009682:Magnetic Resonance Spectroscopy; D008757:Methylglucosides / Q000138:chemical synthesis* / Q000737:chemistry; D011134:Polysaccharides / Q000737:chemistry*; D013402:Sugar Alcohols / Q000138:chemical synthesis
D008757:Methylglucosides; D011134:Polysaccharides; D013402:Sugar Alcohols; D004811:Epichlorohydrin