Multi-residue matrix solid-phase dispersion method for the determination of six synthetic pyrethroids in vegetables followed by gas chromatography with electron capture detection.
An effective multi-residue matrix solid-phase dispersion (MSPD) extraction and gas chromatographic-electron-capture detection method for the determination of six synthetic pyrethroids (fenpropathrin, cyhalothrin, permethrin, cypermethrin, fenvalerate and deltamethrin) in 5 g of vegetables (West Indian gherkin, eggplant, pak-choi, cabbage and garden peas) is described. The method uses a Florisil-based MSPD column for direct in-line clean-up with n-hexane-acetone (9:1). Recoveries calculated at 0.1 and 0.5 micrograms/g fortification levels were between 92 and 113%. The method detection limits were between 5.1 and 91.5 ng/g. The method compared favourably with the traditional method in terms of the sample size, analysis time and overall cost. The method may serve as a screening protocol for the determination of pyrethroids in vegetables.
Ling
Y C
YC
Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan.
Huang
I P
IP
D002849:Chromatography, Gas / Q000379:methods*; D004583:Electrons; D010573:Pesticide Residues / Q000032:analysis*; D011722:Pyrethrins / Q000032:analysis*; D015203:Reproducibility of Results; D014675:Vegetables / Q000737:chemistry*
D010573:Pesticide Residues; D011722:Pyrethrins