Transformation of carbon tetrachloride via sulfur and oxygen substitution by Pseudomonas sp. strain KC.
Pseudomonas sp. strain KC transforms carbon tetrachloride into carbon dioxide and nonvolatile products, without chloroform as an intermediate. To define the pathway for hydrolysis, nonvolatile products were analyzed. Condensation products containing the carbon atom of carbon tetrachloride as carbonyl and thioxo moieties were identified, indicating the intermediacy of phosgene and thiophosgene in the pathway.
Lewis
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TA
Department of Microbiology, Molecular Biology, and Biochemistry, University of Idaho, Moscow 83844-1052, USA.
Crawford
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RL
D001711:Biotransformation; D002245:Carbon Dioxide / Q000378:metabolism; D002251:Carbon Tetrachloride / Q000737:chemistry / Q000378:metabolism*; D008401:Gas Chromatography-Mass Spectrometry; D006868:Hydrolysis; D013058:Mass Spectrometry; D008956:Models, Chemical; D010084:Oxidation-Reduction; D010100:Oxygen / Q000378:metabolism; D010705:Phosgene / Q000031:analogs & derivatives / Q000737:chemistry / Q000378:metabolism; D011549:Pseudomonas / Q000378:metabolism*; D013455:Sulfur / Q000378:metabolism
C016145:thiophosgene; D010705:Phosgene; D002245:Carbon Dioxide; D013455:Sulfur; D002251:Carbon Tetrachloride; D010100:Oxygen