title: Bioelectrocatalysis: the electrochemical kinetics of hydrogenase action.
abstract: A hydrogen electrode based on a hydrogenase immobilized on a carbon material has been developed. The equilibrium hydrogen potential was reached in an atmosphere of H2 on the enzyme electrode according to the mechanism of direct exchange of electrons between the electrode and the enzyme active center. The electrochemical kinetics of the hydrogen enzyme electrode action is presented.
authors.affiliation: Chemical Department, M.V. Lomonosov Moscow State University, Russia.
authors.forename: S D
authors.initials: SD
authors.lastname: Varfolomeyev
authors.forename: A I
authors.initials: AI
authors.lastname: Yaropolov
authors.forename: A A
authors.initials: AA
authors.lastname: Karyakin
mesh_terms: D002384:Catalysis; D002841:Chromatiaceae / Q000201:enzymology; D004563:Electrochemistry / Q000379:methods; D004566:Electrodes; D004800:Enzymes, Immobilized / Q000378:metabolism*; D006864:Hydrogenase / Q000378:metabolism*; D007700:Kinetics
chemical_list: D004800:Enzymes, Immobilized; D006864:Hydrogenase