Oleanane-triterpene saponins from Clinopodium chinense var. parviflorum.
From the whole plants of Clinopodium chinense var. parviflorum three new saponins, named clinoposaponins IX-XI, were isolated together with three known saponins and their structures elucidated from spectroscopic data and chemical evidence. Clinoposaponins IX, X and XI were identified as 13 beta,28-epoxy-16 beta,23-dihydroxyolean-11-en-3 beta-yl-beta-D- glucopyranoside,13 beta,28-epoxy-16 beta,23-dihydroxyolean-11-en-3 beta-yl-beta- D-glucopyranosyl-(1-->6)-beta-D-glucopyranoside and 13 beta,28-epoxy-16 beta-hydroxyolean-11-en-3 beta-yl-beta-D-glucopyranosyl- (1-->2)-[beta-D-glucopyranosyl-(1-->3)]-beta-D-fucopyranoside.
Mori
F
F
School of Pharmaceutical Sciences, University of Shizuoka, Japan.
Miyase
T
T
Ueno
A
A
D002240:Carbohydrate Sequence; D009682:Magnetic Resonance Spectroscopy; D008969:Molecular Sequence Data; D009828:Oleanolic Acid / Q000031:analogs & derivatives*; D010944:Plants / Q000737:chemistry*; D012503:Saponins / Q000737:chemistry* / Q000302:isolation & purification; D016339:Spectrometry, Mass, Fast Atom Bombardment; D014315:Triterpenes / Q000737:chemistry* / Q000302:isolation & purification
D012503:Saponins; D014315:Triterpenes; C090267:clinoposaponin IX; C090268:clinoposaponin X; C090269:clinoposaponin XI; D009828:Oleanolic Acid