(2,3,7,8,12,13,17,18-Octaethylporphinato)perchloratomanganese(III).
The crystal structure of [Mn(OEP)(OClO3)] (where OEP = C36H44N4) has been determined. The axial Mn-O bond length is 2.183 (2) A and the equatorial Mn-Np bond lengths have an average value of 2.000 (5) A. The molecules form weak dimers in the solid state with interring distances of 3.49 A and a lateral shift of 3.27 A. The compound is found to be isomorphous with the iron derivative [Fe(OEP)(OClO3)]. A brief comparison of the structural parameters for the two molecules is given.
Cheng
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Department of Chemistry and Biochemistry, University of Notre Dame, IN 46556, USA.
Scheidt
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D055598:Chemical Phenomena; D002627:Chemistry, Physical; D003460:Crystallization; D018360:Crystallography, X-Ray; D007501:Iron / Q000737:chemistry; D046911:Macromolecular Substances; D008345:Manganese / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*
C094050:(2,3,7,8,12,13,17,18--octaethylporphinato)perchloratomanganese(III); D046911:Macromolecular Substances; D009942:Organometallic Compounds; D011166:Porphyrins; D008345:Manganese; D007501:Iron