Structure of hydrated layers on silicate electrode glasses.
The structural changes of the silicate framework in hydrated layers of silicate electrode glasses compared with untreated glasses as well as the quality and quantity of water and its ionic species stored in the layer have been investigated by high-resolution solid-state nuclear magnetic resonance (NMR) techniques [29Si magic-angle spinning (MAS), 29Si cross-polarization (CP) MAS, 1H high-speed MAS, 1H CRAMPS and 1H Echo NMR]. To support the results, infrared (IR) spectroscopy, thermal analysis and sodium ion concentration analyses were used. It was found that at least two different water species exist in the hydrated layer: SiOH groups and not very mobile hydrogen-bonded molecular water. Concerning the framework modified, Q3 groups [(SiO)3SiOH] were formed in the hydrated glass. During the swelling process a condensation of silanol groups formed took place to a great extent.
Herzog
K
K
Department of Chemistry, University of Mining and Technology, Freiberg, Germany.
Scholz
K
K
Thomas
B
B
D004566:Electrodes; D005898:Glass; D009682:Magnetic Resonance Spectroscopy; D017640:Silicates / Q000737:chemistry*; D014867:Water
D017640:Silicates; D014867:Water