Fitting of low-intensity wide-line spectra dominated by chemical shift anisotropy.
How experimental parameters affect the appearance, and consequently the fitting, of signals having very wide lines is discussed. As these spectra usually have very low intensities, pulse sequences that remove acoustic ringing and other experimental artefacts have to be used. These pulse sequences introduce further spectral distortions. A FORTRAN 77 program was developed that accounts for these effects. The fitting of these broad spectra is demonstrated by application to 207Pb solid-state nuclear magnetic resonance (NMR) spectra.
Neue
G
G
Universität Dortmund, Germany.
Dybowski
C
C
Smith
M L
ML
Barich
D H
DH
D016880:Anisotropy; D009682:Magnetic Resonance Spectroscopy