Solid-state NMR studies of 1H spin diffusion in adsorbed organic molecules.
1H spin diffusion times of toluene (MB) and tetrahydrofuran (THF) adsorbed on a series of porous solids (charcoal, SiO2 and Al2O3) were measured by a selective inversion technique. The experimental results show that they cover a wide range (from less than one millisecond to several hundreds of milliseconds). For all samples, a tri-exponential behavior was observed in the magnetization recovery processes of the negative peaks. This is attributed to the existence of the two different kinds of spin diffusion processes in addition to the T1 relaxation. One is assigned to the intermolecular spin diffusion between the surface acidic protons of the adsorbent and the organic molecules adsorbed on the solid surface, the other to the intramolecular spin diffusion of adsorbed molecules. Due to hydrogen bonding between the surface hydroxyl groups and the adsorbate, the intermolecular spin diffusion of THF adsorbed on various solids is more effective compared to that of adsorbed MB. In addition, the intermolecular 1H spin diffusion between charcoal and adsorbed THF molecules was confirmed by indirect measurement suggested by Tekely et al.
Deng
F
F
State Key Laboratory of Magnetic Resonance, Chinese Academy of Sciences, Wuhan.
Hu
J
J
Xiong
J
J
Du
Y
Y
D002606:Charcoal; D002627:Chemistry, Physical / Q000379:methods; D004058:Diffusion; D005663:Furans / Q000032:analysis / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D014050:Toluene / Q000032:analysis / Q000737:chemistry
D005663:Furans; D002606:Charcoal; D014050:Toluene; C018674:tetrahydrofuran; D006859:Hydrogen