Two-dimensional J-resolved 13C solid-state NMR analysis of the products of ethylene conversion on zeolite H-ZSM-5.
Two-dimensional (2D) J-resolved 13C NMR spectroscopy has been used to analyze the products of ethylene conversion inside the channels of zeolite H-ZSM-5 at 373 K. The observed 13C signals of aliphatic hydrocarbon fragments have been attributed to various CHn (n = 1-3) groups. Multiplicities and positions of these signals suggest that a mixture of branched and linear ethylene oligomers is formed inside zeolite H-ZSM-5.
Stepanov
A G
AG
Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation.
Zudin
V N
VN
Zamaraev
K I
KI
D005030:Ethylenes / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D017641:Zeolites / Q000737:chemistry*
D005030:Ethylenes; D017641:Zeolites; C036216:ethylene