Application of one-dimensional nutation nuclear magnetic resonance to 51V in ferroelastic BiVO4.
The central line intensity of a spin I = 7/2, excited by a radio frequency (rf) pulse, is calculated by taking into account the first-order quadrupolar interaction during excitation. Thus, the result is valid for any ratio of quadrupolar coupling to pulse amplitude. The quadrupolar coupling of the nuclei vanadium 51V in a single crystal of ferroelastic BiVO4 is determined using this one-dimensional (1D) mutation method.
Laboratoire de Chimie des Surfaces, CNRS URA 1428, Université Pierre et Marie Curie, Paris, France.
P P
PP
Man
S H
SH
Choh
J
J
Fraissard
D001729:Bismuth / Q000737:chemistry*; D004548:Elasticity; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D014638:Vanadates / Q000737:chemistry*; D014639:Vanadium
D014639:Vanadium; C091754:bismuth vanadium tetraoxide; D014638:Vanadates; D001729:Bismuth