Correlations between 27Al magic-angle spinning nuclear magnetic resonance spectra and the coordination geometry of framework aluminates.
A range of aluminate sodalites of general formula M8(AlO2)12.X2, where M and X are a divalent cation and anion, respectively, has been synthesised. The structures of these materials, which contain a single aluminum environment, have been refined from powder X-ray or neutron diffraction data and the compounds further characterised using 27Al magic-angle spinning nuclear magnetic resonance (MAS NMR). Correlations between (i) the Al-O-Al bond angles and the 27Al chemical shift and (ii) the quadrupolar coupling constant and the distorted AlO4 tetrahedral geometry have been determined.
Weller
M T
MT
Department of Chemistry, University of Southampton, Highfield, UK.
Brenchley
M E
ME
Apperley
D C
DC
Davies
N A
NA
D000535:Aluminum; D017607:Aluminum Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D008433:Mathematics; D013223:Statistics as Topic
D017607:Aluminum Compounds; D000535:Aluminum