Application of chiral gas chromatography with electroantennographic detection to the determination of the stereochemistry of a cockroach sex pheromone.
The coupling of an electroantennographic detector to a chiral capillary gas chromatographic system provides a highly sensitive technique for the determination of pheromone stereochemistry. Electronic modification of the usual electroantennographic detector enables the detector to respond to the relatively broad peaks produced by chiral gas chromatographic systems. By using this methodology, supellapyrone, a female sex pheromone of the brownbanded cockroach Supella longipalpa (Orthoptera: Blattellidae), is shown to be 5-(2'R,4'R-dimethylheptanyl)-3-methyl-2H-pyran-2-one.
Leal
W S
WS
Department of Chemistry, Cornell University, Ithaca, NY 14853.
Shi
X
X
Liang
D
D
Schal
C
C
Meinwald
J
J
D000818:Animals; D002849:Chromatography, Gas / Q000379:methods*; D003058:Cockroaches / Q000737:chemistry*; D004563:Electrochemistry; D005260:Female; D008297:Male; D012724:Sex Attractants / Q000737:chemistry* / Q000302:isolation & purification; D013237:Stereoisomerism
D012724:Sex Attractants