[A transformylation reaction--transfer of an N-formyl residue to amino acids and peptides in nucleophilic groups--as a side reaction of peptide synthesis].
The formyl group transfer from N-formyl amino acids and their derivatives to other acceptors--amino acids esters and aniline, was studied. Formylamino acids with the free alpha-carboxyl group are more effective donors in transformylation than formyl peptides or esters of formylamino acids.
Kotlova
E K
EK
Levin
E D
ED
Iusupova
M P
MP
Rozynov
B V
BV
Stepanov
V M
VM
D000217:Acyltransferases / Q000737:chemistry*; D000596:Amino Acids / Q000737:chemistry*; D002264:Carboxylic Acids; D002851:Chromatography, High Pressure Liquid; D004952:Esters; D019877:Hydroxymethyl and Formyl Transferases; D013058:Mass Spectrometry; D010455:Peptides / Q000737:chemistry*
D000596:Amino Acids; D002264:Carboxylic Acids; D004952:Esters; D010455:Peptides; D019877:Hydroxymethyl and Formyl Transferases; C021561:methionyl-tRNA formyltransferase; D000217:Acyltransferases
Reaktsiia transformilirovaniia--perenos N-formil'nogo ostatka v proizvodnykh aminokislot i peptidov na nukleofil'nye gruppy--kak pobochnaia reaktsiia peptidnogo sinteza.