title: Platinum(II) triamine complexes: cis-[PtCl(NH3)2(C10H13N5O5)]NO3.2H2O and [PtCl(C2H8N2)(C4H6N2)]NO3.
abstract: The structures of cis-diamminechloro(guanosine-N7)-platinum(II) nitrate dihydrate, cis-[PtCl(NH3)2-(C10H13N5O5)]NO3.2H2O, (I), and chloro(ethylenediamine)(1-methylimidazole-N3)platinum(II) nitrate, [PT-(C2H8N2)(C4H6N2)Cl]NO3, [PtCl(en)(1-MeIm)]NO3, (II), were determined by single-crystal X-ray diffraction. The former complex crystallized in the orthorhombic system and the latter in the monoclinic system. In compound (I), water molecules were found to connect the metal complex with the nitrate counter ions via hydrogen bonding.
authors.affiliation: Trenton State College, Hillwood Lakes, New Jersey 08650.
authors.forename: G M
authors.initials: GM
authors.lastname: Arvanitis
authors.forename: D
authors.initials: D
authors.lastname: Gibson
authors.forename: T J
authors.initials: TJ
authors.lastname: Emge
authors.forename: H M
authors.initials: HM
authors.lastname: Berman
mesh_terms: D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D015394:Molecular Structure; D009944:Organoplatinum Compounds / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D009944:Organoplatinum Compounds; C090301:chloro(ethylenediamine)(1-methylimidazole-N(3))platinum(II); C090300:diamminechloro(guanosine-N(7))platinum(II)