Effects of sandblasting and silica-coating procedures on pure titanium.
Silica coating titanium improves chemomechanical bonding. Sandblasting is recommended as a pretreatment to thermal silica coating (Silicoater MD) or as part of a tribochemical silica coating process (Rocatec). This study evaluated the effects of sandblasting and coating techniques on volume loss, surface morphology and composition changes in pure titanium. Volume loss of titanium was similar to values reported for base alloys and does not seem to be critical for the clinical fit of restorations. Embedded alumina particles were found in the titanium after sandblasting and the alumina content increased to a range of 27.5-39.3 wt% as measured by EDS. Following tribochemical silica coating, a layer of small silica particles remained on the surface, increasing the silica content to a range of 17.9-19.5 wt%. Ultrasonic cleaning removed loose alumina or silica particles from the surface, resulting in only slight decreases in alumina or silica contents, suggesting firm attachment of most of the alumina and silica to the titanium surface. Silica content following thermal silica coating treatment increased only slightly from the sandblasted specimen to 1.4 wt%. The silica layer employed by these silica coating methods differs widely in both morphology and thickness. These results provide a basis for explanation of adhesive failure modes in bond strength tests and for developing methods to optimize resin bonding. Clinically, ultrasonic cleaning of sandblasted and tribochemically silica coated titanium should improve resin bonding as loose surface particles are removed without relevant changes in composition.
Department of Restorative Dentistry, Dental School, University of Maryland, Baltimore.
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D000537:Aluminum Oxide / Q000737:chemistry; D000704:Analysis of Variance; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D001840:Dental Bonding; D003775:Dental Polishing; D004577:Electron Probe Microanalysis; D008422:Materials Testing; D008855:Microscopy, Electron, Scanning; D012821:Silanes / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry; D018709:Statistics, Nonparametric; D013499:Surface Properties; D014025:Titanium / Q000737:chemistry*; D014465:Ultrasonics
D012821:Silanes; D012822:Silicon Dioxide; D014025:Titanium; D000537:Aluminum Oxide