Determination of strontium-90 in water and urine samples using ion chromatography.
A semi-automated method was developed for the determination of 90Sr in water and urine samples using ion chromatography. Yttrium-90 in secular equilibrium with 90Sr was initially extracted from the sample solution buffered to pH 5 using a high-capacity iminodiacetate chelating resin. At this pH, transition metals, lanthanides and actinides were extracted by the resin. The extracted metals were then transferred on to a separator column where they were separated and eluted as weak acid anionic complexes. The transition metals were eluted first by using a pyridine-2,6-dicarboxylate eluent, then the lanthanides, actinides and 90Y were eluted from the column by using an oxalate-diglycolate eluent. The fraction containing 90Y was then collected and beta-counted. For water samples, a minimum of sample preparation was required prior to chromatography, whereas an oxalate coprecipitation was included as a preconcentration step for urine samples. The derived recoveries for 90Sr for surface water, rain water and urine samples were 91.7 +/- 1.8, 91.9 +/- 1.6 and 90.0 +/- 2.7%, respectively, and the minimum detectable activity using gas flow proportional counting was 8 mBq.
Cobb
J
J
Department of Chemistry, Loughborough University of Technology, UK.
Warwick
P
P
Carpenter
R C
RC
Morrison
R T
RT
D002845:Chromatography; D006801:Humans; D013326:Strontium Radioisotopes / Q000032:analysis* / Q000652:urine; D014875:Water Pollutants, Radioactive / Q000032:analysis*
D013326:Strontium Radioisotopes; D014875:Water Pollutants, Radioactive