On the possibility of performing chiral wall-coated open-tubular electrochromatography in 50 micron internal diameter capillaries.
Recent results have demonstrated acceptable enantiomer separations in open, 50 microns internal diameter capillaries, coated with a chiral stationary phase, a technique known as electrochromatography. According to existing literature, smaller column diameters, 10 microns or less, are generally preferred for this mode of operation. The conditions under which the wider columns can be used are discussed.
Vindevogel
J
J
Department of Organic Chemistry, University of Gent, Belgium.
Sandra
P
P
D002845:Chromatography / Q000295:instrumentation / Q000379:methods*; D004058:Diffusion; D004563:Electrochemistry; D013237:Stereoisomerism