An unusual C-4a hydroxylated decahydroquinolone.
The crystal structure and the relative stereochemistry of the four asymmetric centers of an unusual C-4a hydroxylated decahydroquinolone, phenyl 1,2 alpha,3,4,-4a alpha,5 beta,6,7,8,8a alpha-decahydro-4a-hydroxy-4-oxo-2-propyl-5-vinylquinoline-1 -carboxylate, C21H27NO4, are reported. The H and OH groups at the ring juncture are cis to each other as are the two H atoms alpha to the N atom. The vinyl and OH groups are also cis to each other. The N atom is sp2 hybridized.
Joseph
S P
SP
Department of Chemistry, North Carolina State University, Raleigh 27695-8204.
Comins
D L
DL
Singh
P
P
D003460:Crystallization; D018360:Crystallography, X-Ray; D015394:Molecular Structure; D015363:Quinolones / Q000737:chemistry*
D015363:Quinolones; C088583:decahydro-4a-hydroxy-4-oxo-2-propyl-5-vinylquinoline-1-carboxylic acid phenyl ester