Fast atom bombardment mass spectrometry of elymoclavine glycosides.
A series of nine naturally occurring and/or semi-synthetic elymoclavine mono- and oligoglycosides containing various sugar units was investigated by fast atom bombardment, high-resolution measurements and linked scans. The fragmentations of the [M+H]+ and [M+Na]+ ions are described and their different contributions to the structure elucidation are discussed.
Havlícek
V
V
Institute of Microbiology, Academy of Sciences of the Czech Republic, Prague.
Flieger
M
M
Kren
V
V
Ryska
M
M
D002240:Carbohydrate Sequence; D004873:Ergolines / Q000737:chemistry*; D008969:Molecular Sequence Data; D016339:Spectrometry, Mass, Fast Atom Bombardment
D004873:Ergolines; C007586:elymoclavine