title: Spatially resolved NMR of rigid polymers and elastomers.
abstract: NMR imaging with protons is becoming a more and more versatile tool for material research. Two different approaches are presented to obtain spatial resolution in elastomers and solids. The first, magic-sandwich-echo-imaging, belongs to the group of multiple-pulse techniques which are applied to overcome the strong dipolar couplings in solids. A driver for fast gradient pulses was constructed, and the technique was used to measure one-dimensional projections and spatially resolved spectra of rigid polymers. The second approach uses surface coils. In this way large objects can be investigated from the surface at optimum signal to noise. The drawback of the inhomogeneous B1 field resulting in signal attenuation across the image can be overcome by imaging an NMR parameter like the relaxation time T2. This was applied to image a phantom of different polyurethane foams. Furthermore spin-echo images of signal intensity maps around conducting wires are presented for the analysis of current distributions.
authors.affiliation: Max-Planck-Institut für Polymerforschung, Mainz, Germany.
authors.forename: F
authors.initials: F
authors.lastname: Weigand
authors.forename: C
authors.initials: C
authors.lastname: Fülber
authors.forename: B
authors.initials: B
authors.lastname: Blümich
authors.forename: H W
authors.initials: HW
authors.lastname: Spiess
mesh_terms: D008279:Magnetic Resonance Imaging; D009682:Magnetic Resonance Spectroscopy; D011108:Polymers; D012408:Rubber
chemical_list: D011108:Polymers; D012408:Rubber