Anhydro sugars and oligosaccharides from the thermolysis of sucrose.
Thermolysis of anhydrous, amorphous, acidified sucrose results in polymerization initially involving the fructosyl cation and later the glucosyl cation. Monomeric and dimeric anhydro sugars form during the thermolysis and are incorporated into the fructoglucan polymer.
Manley-Harris
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M
Wood Chemistry Laboratory, University of Montana, Missoula 59812.
Richards
G N
GN
D000812:Anhydrides; D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D002855:Chromatography, Thin Layer; D004187:Disaccharides / Q000138:chemical synthesis / Q000737:chemistry*; D005632:Fructose; D005947:Glucose; D006358:Hot Temperature; D006868:Hydrolysis; D009682:Magnetic Resonance Spectroscopy; D008969:Molecular Sequence Data; D009005:Monosaccharides / Q000138:chemical synthesis / Q000737:chemistry*; D009844:Oligosaccharides / Q000138:chemical synthesis / Q000737:chemistry*; D013395:Sucrose / Q000737:chemistry*
D000812:Anhydrides; D004187:Disaccharides; D009005:Monosaccharides; D009844:Oligosaccharides; D005632:Fructose; D013395:Sucrose; D005947:Glucose