title: Fabrication and characterization of low-loss, sol-gel planar waveguides.
abstract: Applications of planar integrated optical waveguide (IOW) technology to problems in surface spectroscopy and optical chemical sensing have been partly limited by the difficulty of producing high-quality glass IOWs. The fabrication of IOWs by the sol-gel method from methyltriethoxysilane and titanium tetrabutoxide precursors is described here. The physical, chemical, and optical properties of the films during and after high-temperature annealing were studied using a variety of analytical techniques. The results show that the catalyst used to accelerate the sol-gel reaction strongly influenced the optical quality of the IOW. HCl catalysis produced waveguides with propagation losses of approximately 1 dB/cm, whereas in the case of SiCl4 catalysis, propagation losses were < 0.2 dB/cm, a value significantly less than any previously reported for sol-gel-derived IOWs. An examination of film surface structure and morphology by scanning electron microscopy and atomic force microscopy showed that the SiCl4-catalyzed IOWs were significantly smoother and more homogeneous on a submicrometer scale than the HCl-catalyzed IOWs. The use of SiCl4 is thought to retard formation of a microheterogeneous network containing Si-rich and Ti-rich domains, which is favored with HCl catalysis and contributes to the higher observed losses.
authors.affiliation: Department of Chemistry, University of Arizona, Tucson 85721.
authors.forename: L
authors.initials: L
authors.lastname: Yang
authors.forename: S S
authors.initials: SS
authors.lastname: Saavedra
authors.forename: N R
authors.initials: NR
authors.lastname: Armstrong
authors.forename: J
authors.initials: J
authors.lastname: Hayes
mesh_terms: D005336:Fiber Optic Technology / Q000295:instrumentation*; D005782:Gels
chemical_list: D005782:Gels