Autoxidation kinetics of aqueous nitric oxide.
Reports on the kinetics of the autoxidation of aqueous nitric oxide are discussed. It is concluded that the correct rate law is -d[NO]/dt = 4kaq[NO]2[O2] with kaq = 2 x 10(6) M-2.s-1 at 25 degrees c and that a recent report of a rate law zero order in NO is incorrect.
Ford
P C
PC
Department of Chemistry, University of California, Santa Barbara 97106.
Wink
D A
DA
Stanbury
D M
DM
D007700:Kinetics; D009569:Nitric Oxide / Q000378:metabolism*; D010084:Oxidation-Reduction; D012996:Solutions; D013053:Spectrophotometry; D014867:Water
D012996:Solutions; D014867:Water; D009569:Nitric Oxide