Shape-selective separation of polycyclic aromatic hydrocarbons by reversed-phase liquid chromatography on tetraphenylporphyrin-based stationary phases.
The reversed-phase chromatographic behavior of planar and non-planar polycyclic aromatic hydrocarbons (PAHs) is investigated on tetraphenylporphyrin and two metallotetraphenylporphyrin [Sn(IV), In(III)] bonded stationary phases using methanol-water and acetonitrile-water as mixed solvent mobile phases. Large differences in the capacity factors of aromatic solute pairs having the same number of carbon atoms, but differing in three-dimensional shape (e.g., triphenylene/o-terphenyl and perylene/alpha, alpha'-binaphthyl), suggest that the three tetraphenylporphyrin-based supports possess shape selectivity toward small planar aromatic solutes. Capacity factors for planar PAH solutes on these supports are significantly greater than for non-planar polyaryls having the same number of carbon atoms.
Kibbey
C E
CE
Department of Chemistry, University of Michigan, Ann Arbor 48109.
Meyerhoff
M E
ME
D002851:Chromatography, High Pressure Liquid / Q000379:methods*; D008665:Metalloporphyrins / Q000737:chemistry*; D011083:Polycyclic Compounds / Q000302:isolation & purification*; D013056:Spectrophotometry, Ultraviolet
D008665:Metalloporphyrins; D011083:Polycyclic Compounds