Imaging fluid/solid interactions in hydrocarbon reservoir rocks.
The environmental scanning electron microscope (ESEM) has been used to image liquid hydrocarbons in sandstones and oil shales. Additionally, the fluid sensitivity of selected clay minerals in hydrocarbon reservoirs was assessed via three case studies: HCl acid sensitivity of authigenic chlorite in sandstone reservoirs, freshwater sensitivity of authigenic illite/smectite in sandstone reservoirs, and bleach sensitivity of a volcanic reservoir containing abundant secondary chlorite/corrensite. The results showed the suitability of using ESEM for imaging liquid hydrocarbon films in hydrocarbon reservoirs and the importance of simulating in situ fluid-rock interactions for hydrocarbon production programmes. In each case, results of the ESEM studies greatly enhanced prediction of reservoir/borehole reactions and, in some cases, contradicted conventional wisdom regarding the outcome of potential engineering solutions.
Centre for Microscopy and Microanalysis, University of Queensland, Brisbane, Australia.
P J
PJ
Uwins
J C
JC
Baker
I D
ID
Mackinnon
D000538:Aluminum Silicates; D000077215:Clay; D004577:Electron Probe Microanalysis; D006838:Hydrocarbons; D006851:Hydrochloric Acid; D008855:Microscopy, Electron, Scanning; D010578:Petroleum; D011791:Quartz; D012822:Silicon Dioxide / Q000737:chemistry*; D014867:Water
D000538:Aluminum Silicates; D006838:Hydrocarbons; D010578:Petroleum; D014867:Water; D011791:Quartz; D012822:Silicon Dioxide; D006851:Hydrochloric Acid; D000077215:Clay