title: Effects of initial temperature and tempering medium on thermal tempering of dental porcelains.
abstract: The objective of this study was to test the hypothesis that quenching of porcelain in silicone oil rather than in compressed air will significantly increase the flexure strength by reducing the potential for crack formation during transient cooling. A secondary hypothesis to be tested is that the initial tempering temperature can be reduced significantly below the porcelain maturing temperature of 982 degrees C but well above Tg without a decrease in strength. Opaque-body porcelain disks, 16 mm in diameter and 2 mm in thickness, with a thermal contraction mismatch (delta alpha) of -1.5, 0, and +3.2 ppm/degrees C were tempered from initial temperatures of 650, 750, 850, and 982 degrees C in silicone oil with kinematic viscosities of 50, 1000, and 5000 centistokes. Porcelain disks were also subjected to three cooling procedures in air: slow cooling in a furnace (SC), free convective cooling in a laboratory bench (FC), and tempering (T) by blasting the surface of body porcelain with air. The crack size induced by a Vickers microhardness indenter was measured within one minute after crack development. For determination of the influence of initial cooling temperature on biaxial flexure strength, six body porcelain disks (delta alpha = 0) were tempered in air from initial temperatures of 650, 750, 850, and 982 degrees C. The mean crack size of specimens tempered in oil was significantly smaller (p < or = 0.001) than that of specimens that were slowly-cooled or fast-cooled in air for all thermal contraction mismatch cases.(ABSTRACT TRUNCATED AT 250 WORDS)
authors.affiliation: Department of Dental Biomaterials, College of Dentistry, University of Florida, Gainesville 32610-0446.
authors.forename: B
authors.initials: B
authors.lastname: Hojjatie
authors.forename: K J
authors.initials: KJ
authors.lastname: Anusavice
mesh_terms: D000538:Aluminum Silicates / Q000737:chemistry; D000704:Analysis of Variance; D003735:Dental Casting Technique / Q000295:instrumentation; D003776:Dental Porcelain / Q000737:chemistry*; D004548:Elasticity; D006244:Hardness; D006358:Hot Temperature; D008422:Materials Testing; D011188:Potassium / Q000737:chemistry; D017680:Potassium Compounds; D012827:Silicone Oils / Q000737:chemistry*; D013314:Stress, Mechanical; D013499:Surface Properties; D013696:Temperature; D013718:Tensile Strength; D013814:Thermal Conductivity; D013816:Thermodynamics; D014783:Viscosity
chemical_list: D000538:Aluminum Silicates; D017680:Potassium Compounds; D012827:Silicone Oils; D003776:Dental Porcelain; C016447:feldspar; D011188:Potassium