Reinvestigation of the structure of the esterified cerebroside in the epidermis of guinea pigs.
One of the esterified cerebroside in the epidermis of guinea pigs is shown to be (2S,3R,4E,23'Z)-1-O-(beta-D-glucopyranosyl)-N-(32'-linoleoyloxy  -23'-dotriacontenoyl)-4-sphingenine by chemical and spectroscopic studies.
Department of Agricultural Chemistry, University of Tokyo, Japan.
H
H
Nishio
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K
Mori
D000818:Animals; D002554:Cerebrosides / Q000138:chemical synthesis / Q000737:chemistry* / Q000302:isolation & purification; D002849:Chromatography, Gas; D002851:Chromatography, High Pressure Liquid; D004817:Epidermis / Q000737:chemistry*; D005227:Fatty Acids / Q000032:analysis / Q000737:chemistry; D006168:Guinea Pigs; D019787:Linoleic Acid; D008041:Linoleic Acids / Q000032:analysis / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D000432:Methanol / Q000737:chemistry; D008970:Molecular Weight; D013110:Sphingosine / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry
C097141:1-O-glucopyranosyl-N-(32'-linoleoyloxy-23'-dotriacontenoyl)-4-sphingenine; D002554:Cerebrosides; D005227:Fatty Acids; D008041:Linoleic Acids; D019787:Linoleic Acid; D013110:Sphingosine; D000432:Methanol