Karsoside and scropolioside D, two new iridoid glycosides from Scrophularia ilwensis.
Two new iridoid glycosides, karsoside [1] and scropolioside D [2], were isolated from the aerial parts of Scrophularia ilwensis. Their structures were elucidated on the basis of chemical and spectral data as 6'-O-(beta-D-xylopyranosyl)-methylcatalpol and 6-O-[(2",4"-di-O-acetyl-3"-O-trans-cinnamoyl)-alpha-L-rhamnopyranosyl]- catalpol, respectively. Additionally, four known iridoids (aucubin, harpagide, 8-O-acetylharpagide, and ajugol), a phenylpropanoid glycoside (angoroside C), and two flavonoids (quercetin-3-O-rutinoside and kaempferol-3-O-rutinoside) were isolated and identified.
Department of Pharmacognosy, Faculty of Pharmacy, Hacettepe University, Ankara, Turkey.
I
I
Caliş
M
M
Zor
A A
AA
Başaran
A D
AD
Wright
O
O
Sticher
D000107:Acetylation; D006027:Glycosides / Q000302:isolation & purification* / Q000494:pharmacology; D006868:Hydrolysis; D057888:Iridoid Glucosides; D039823:Iridoids; D009682:Magnetic Resonance Spectroscopy; D010946:Plants, Medicinal / Q000737:chemistry*; D011714:Pyrans / Q000302:isolation & purification* / Q000494:pharmacology; D016339:Spectrometry, Mass, Fast Atom Bombardment; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet
D006027:Glycosides; D057888:Iridoid Glucosides; D039823:Iridoids; D011714:Pyrans; C081264:scropolioside D; C081263:karsoside