An unusual rearrangement product formed during production of mometasone furoate (Sch 32088).
The structure of an unusual rearrangement product obtained during the production of mometasone furoate (Sch 32088) was assigned on the basis of NMR and X-ray crystallography data.
Schering-Plough Research Institute, Kenilworth, New Jersey 07033-0539, USA.
M S
MS
Puar
P A
PA
Thompson
M
M
Ruggeri
D
D
Beiner
A T
AT
McPhail
D000287:Administration, Topical; D000893:Anti-Inflammatory Agents / Q000138:chemical synthesis; D018360:Crystallography, X-Ray; D005938:Glucocorticoids; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D000068656:Mometasone Furoate; D011244:Pregnadienediols / Q000138:chemical synthesis* / Q000737:chemistry; D011281:Pregnatrienes / Q000138:chemical synthesis* / Q000737:chemistry
C097571:9,21-dichloro-20-((2'-furanylcarbonyl)oxy)-11-hydroxy-16,17-dimethyl-18-norpregna-1,4,13,20-tetraen-3-one; D000893:Anti-Inflammatory Agents; D005938:Glucocorticoids; D011244:Pregnadienediols; D011281:Pregnatrienes; D000068656:Mometasone Furoate