title: Stereostructure of Rimocidin.
abstract: NMR studies of rimocidin, consisting of DQF-COSY, ROESY, HSQC, HMBC and 1D-TOCSY experiments, resulted in the assignment of the absolute configuration of the rimocidin chiral centers as 2S, 3R, 9S, 11R, 13S, 14R, 15S, 17R, and 27R. The geometry of tetraene chromophore was found to be all-trans.
authors.affiliation: Department of Drug Technology and Biochemistry, Technical University of Gdańsk, Poland.
authors.forename: P
authors.initials: P
authors.lastname: Sowiński
authors.forename: J
authors.initials: J
authors.lastname: Pawlak
authors.forename: E
authors.initials: E
authors.lastname: Borowski
authors.forename: P
authors.initials: P
authors.lastname: Gariboldi
mesh_terms: D000935:Antifungal Agents / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008968:Molecular Conformation; D015394:Molecular Structure; D011090:Polyenes / Q000737:chemistry
chemical_list: D000935:Antifungal Agents; D011090:Polyenes; C003273:rimocidin