Stereostructure of Rimocidin.
NMR studies of rimocidin, consisting of DQF-COSY, ROESY, HSQC, HMBC and 1D-TOCSY experiments, resulted in the assignment of the absolute configuration of the rimocidin chiral centers as 2S, 3R, 9S, 11R, 13S, 14R, 15S, 17R, and 27R. The geometry of tetraene chromophore was found to be all-trans.
Sowiński
P
P
Department of Drug Technology and Biochemistry, Technical University of Gdańsk, Poland.
Pawlak
J
J
Borowski
E
E
Gariboldi
P
P
D000935:Antifungal Agents / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008968:Molecular Conformation; D015394:Molecular Structure; D011090:Polyenes / Q000737:chemistry
D000935:Antifungal Agents; D011090:Polyenes; C003273:rimocidin