Shape-Controlled Synthesis of Colloidal Platinum Nanoparticles
The shapes and sizes of platinum nanoparticles were controlled by changes in the ratio of the concentration of the capping polymer material to the concentration of the platinum cations used in the reductive synthesis of colloidal particles in solution at room temperature. Tetrahedral, cubic, irregular-prismatic, icosahedral, and cubo-octahedral particle shapes were observed, whose distribution was dependent on the concentration ratio of the capping polymer material to the platinum cation. Controlling the shape of platinum nanoparticles is potentially important in the field of catalysis.
Ahmadi
TS
T. S. Ahmadi, T. C. Green, M. A. El-Sayed, School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332, USA. Z. L. Wang, School of Material Sciences and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA. A. Henglein, Hahn-Meitner Institut, Abteilung Kleinteilchenforschung, 14109 Berlin, Germany.
Wang
ZL
Green
TC
Henglein
A
El-Sayed
MA