title: Multiresidue method for determination of organophosphorus insecticide residues in fatty processed foods by gel permeation chromatography.
abstract: A multiresidue method for quantitative determination of 39 organophosphorus compounds (parent pesticides and their major metabolites) in 7 fatty processed foods is described. Samples are extracted with methylene chloride and cleaned up by automated gel permeation chromatography with a Biobeads SX3 column and a methylene chloride-cyclohexane (15 + 85) eluant. Organophosphorus compounds are quantitated by capillary gas-liquid chromatography with flame photometric detection using OV-1701 and DB-5 columns. Average recoveries from samples fortified at 0.025-1 mg/kg ranged from 50.6% for dichlorvos to 185% for malaoxon. Determination limits were between 0.005 and 0.040 micrograms/mL. Results were confirmed by gas chromatography/mass spectrometry with selected-ion monitoring.
authors.affiliation: Stazione Sperimentale per L'Industria delle Conserve Alimentari, Parma, Italy.
authors.forename: A
authors.initials: A
authors.lastname: Sannino
authors.forename: P
authors.initials: P
authors.lastname: Mambriani
authors.forename: M
authors.initials: M
authors.lastname: Bandini
authors.forename: L
authors.initials: L
authors.lastname: Bolzoni
mesh_terms: D002850:Chromatography, Gel; D004041:Dietary Fats / Q000032:analysis*; D005504:Food Analysis; D005506:Food Contamination; D005511:Food Handling; D008401:Gas Chromatography-Mass Spectrometry; D007306:Insecticides / Q000032:analysis* / Q000378:metabolism; D009943:Organophosphorus Compounds; D010573:Pesticide Residues / Q000032:analysis*; D015203:Reproducibility of Results
chemical_list: D004041:Dietary Fats; D007306:Insecticides; D009943:Organophosphorus Compounds; D010573:Pesticide Residues