title: Bonded cellulose-derived high-performance liquid chromatography chiral stationary phases. I. Influence of the degree of fixation on selectivity.
abstract: Four mixed 10-undecenoyl-3,5-dimethylphenylaminocarbonyl derivatives of cellulose, with an increasing proportion of alkenoyl groups, were synthesized and chemically bonded on allylsilica gel. The influence of the degree of fixation of the cellulose derivative on the matrix for the four resulting chiral stationary phases on their selectivity is discussed.
authors.affiliation: Laboratori de Química Farmacèutica, Facultat de Farmàcia, Universitat de Barcelona, Spain.
authors.forename: C
authors.initials: C
authors.lastname: Minguillón
authors.forename: P
authors.initials: P
authors.lastname: Franco
authors.forename: L
authors.initials: L
authors.lastname: Oliveros
authors.forename: P
authors.initials: P
authors.lastname: López
mesh_terms: D002482:Cellulose / Q000737:chemistry*; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D002851:Chromatography, High Pressure Liquid / Q000379:methods*; D008140:Lorazepam / Q000737:chemistry / Q000302:isolation & purification; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D011433:Propranolol / Q000737:chemistry / Q000302:isolation & purification; D017433:Protein Structure, Secondary; D012995:Solubility; D013237:Stereoisomerism
chemical_list: D002482:Cellulose; D011433:Propranolol; D008140:Lorazepam