title: A new linear solvation energy relationship for the solubility of liquids in water.
abstract: From a comparison between the linear solvation energy relationship (LSER) and the extended solubility parameter model, it has been found that the solute-solute interaction energy term is missing in the LSER equation. A new LSER equation with the supplementary interaction energy term has been proposed for the solvation process. It is shown that the new LSER equation yields the correct solute-solvent interaction terms for the solubilities of liquids in water.
authors.affiliation: Department of Chemical Engineering, Pohang University of Science and Technology, Korea.
authors.forename: S B
authors.initials: SB
authors.lastname: Lee
mesh_terms: D016014:Linear Models; D004364:Pharmaceutical Preparations / Q000737:chemistry*; D012995:Solubility; D014867:Water / Q000737:chemistry*
chemical_list: D004364:Pharmaceutical Preparations; D014867:Water