A new linear solvation energy relationship for the solubility of liquids in water.
From a comparison between the linear solvation energy relationship (LSER) and the extended solubility parameter model, it has been found that the solute-solute interaction energy term is missing in the LSER equation. A new LSER equation with the supplementary interaction energy term has been proposed for the solvation process. It is shown that the new LSER equation yields the correct solute-solvent interaction terms for the solubilities of liquids in water.
Lee
S B
SB
Department of Chemical Engineering, Pohang University of Science and Technology, Korea.
D016014:Linear Models; D004364:Pharmaceutical Preparations / Q000737:chemistry*; D012995:Solubility; D014867:Water / Q000737:chemistry*
D004364:Pharmaceutical Preparations; D014867:Water