title: Hydroxyapatite/metal composite coatings formed by electrocodeposition.
abstract: Early bone infusion by cementless fixation of composite orthopedic and dental implants consisting of metallic substrates and bioceramics is well documented. Calcium phosphate ceramics in general and hydroxyapatite (HA) in particular have been the most popular of the bioceramics used for coating metals. Here, a non-line of sight coating procedure by electrocodeposition is reported for mechanically fixing HA particles in a metal matrix. Analyses of the coating showed excellent adhesion to the substrate and no structural transformation in either crystallinity or stoichiometry. Adhesion and surface coverage of HA depended upon the particle size. As a demonstration of the coating procedure's non-line of sight applicability, it was successfully used to coat titanium rods sintered with small titanium spheres.
authors.affiliation: Department of chemistry and Materials Science, University of Alabama in Huntsville 35899, USA.
authors.forename: H
authors.initials: H
authors.lastname: Dasarathy
authors.forename: C
authors.initials: C
authors.lastname: Riley
authors.forename: H D
authors.initials: HD
authors.lastname: Coble
authors.forename: W R
authors.initials: WR
authors.lastname: Lacefield
authors.forename: G
authors.initials: G
authors.lastname: Maybee
mesh_terms: D001672:Biocompatible Materials; D002516:Ceramics; D003776:Dental Porcelain; D017886:Durapatite; D004563:Electrochemistry / Q000379:methods; D006801:Humans; D008670:Metals; D008855:Microscopy, Electron, Scanning; D019736:Prostheses and Implants; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman
chemical_list: D001672:Biocompatible Materials; D008670:Metals; D003776:Dental Porcelain; D017886:Durapatite