Steroid alkaloid glycosides from Solanum coccineum.
In addition to solamargine, isoanguivine and solasonine, two new steroid alkaloid glycosides, xylosylsolamargine and xylosyl-beta-solamarine, have been isolated from the aerial parts of Solanum coccineum, the structures of which have been elucidated as (25R)-3 beta-[O-beta-D-xylopyranosyl-(1-->2)-O-alpha-L-rhamnopyranosyl- (1-->4)-O-[alpha-L-rhamnopyranosyl-(1-->2)]-beta-D-glucopyranosyloxy+ ++]-22 alpha N-spirosol-5-ene and (25S)-3 beta-[O-beta-D-xylopyranosyl-(1-->2)-O-alpha-L-rhamnopyranosyl- (1-->4)-O-[alpha-L-rhamnopyranosyl-(1-->2)]-beta-D-glucopyranosyloxy+ ++]-22 beta N-spirosol-5-ene.
Lorey
S
S
Institute of Plant Biochemistry, Halle, Germany.
Porzel
A
A
Ripperger
H
H
D000470:Alkaloids / Q000737:chemistry* / Q000302:isolation & purification; D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D006027:Glycosides / Q000737:chemistry* / Q000302:isolation & purification; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D008969:Molecular Sequence Data; D015394:Molecular Structure; D009844:Oligosaccharides / Q000737:chemistry* / Q000302:isolation & purification; D010944:Plants; D013256:Steroids / Q000737:chemistry* / Q000302:isolation & purification
D000470:Alkaloids; D006027:Glycosides; D009844:Oligosaccharides; D013256:Steroids