Detection of multiple boron sites in glasses by 11B satellite transition nuclear magnetic resonance spectroscopy.
The magic-angle spinning sidebands of the satellite transition (ST, m = +/- 3/2 <==> +/- 1/2) for 11B nuclear magnetic resonance (11B ST spectroscopy) have been used to detect multiple boron sites in Na2O-B2O3-SiO2 glasses. The experimental details and data analysis are described, how multiple BO4 and BO3 units can be distinguished using standard magic-angle spinning. For a 16Na2O-30B2O3-53.9SiO2 glass (0.1 MnO) two BO4 units with chemical shifts of -2.5 and 0 ppm were found which differ considerably in their quadrupole interaction. Besides this we found three different BO3 units with approximate chemical shifts of 17, 15, and 19 ppm. The results are compared with earlier measurements.
Jäger
C
C
Max-Planck-Institut für Polymerforschung, Mainz, Germany.
Herzog
K
K
Thomas
B
B
Feike
M
M
Kunath-Fandrei
G
G
D001895:Boron / Q000032:analysis*; D001896:Boron Compounds / Q000737:chemistry; D005898:Glass / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D010087:Oxides / Q000737:chemistry; D012822:Silicon Dioxide / Q000737:chemistry; D017670:Sodium Compounds / Q000737:chemistry
D001896:Boron Compounds; D010087:Oxides; D017670:Sodium Compounds; C096707:sodium oxide; C042168:boron oxide; D012822:Silicon Dioxide; D001895:Boron