Assessment of airborne hexavalent chromium in the home following use of contaminated tapwater.
Field studies were conducted to estimate the plausible uptake of hexavalent chromium [Cr(VI)] aerosols inhaled during indoor residential use of a shower or an evaporative cooler supplied with water containing Cr(VI). In the evaporative cooler study, water concentrations of 20 mg Cr(VI)/L did not produce an increased concentration of airborne Cr(VI). The indoor air concentration of Cr(VI), measured over 24 hours of use, was 0.3-2.7 ng/m3, about the same as the concurrent outdoor concentrations. In the shower study, the average airborne concentrations of Cr(VI) aerosols at breathing-zone height ranged from 87 to 324 ng Cr(VI)/m3 when the water concentration of Cr(VI) was 0.89 to 11.5 mg/L. The Cr(VI) concentration in air was correlated directly to water concentration. The lifetime average daily doses and incremental cancer risk estimates corresponding to 30-year residential exposures were calculated using the measurements in this study and published exposure guidelines. The plausible upperbound lifetime cancer risk associated with continuous exposure to "background" Cr(VI) in outdoor air was estimated at 6.9 per million for a person exposed during ages 0-30, and 4.0 per million for ages 30-60. Similarly estimated upperbound cancer risks due to inhalation of shower aerosols from water containing 2-10 mg Cr(VI)/L over the same exposure period ranged from 0.9 to 5.5 per million. Our calculations demonstrate that shower aerosols do not contribute appreciably to background Cr(VI) exposures and risks, even at concentrations exceeding 2 mg Cr(VI)/L, which exhibit a discernible and unaesthetic yellow color that may limit the potential for long-term exposures of this type. We conclude that exposure to indoor aerosols from water containing Cr(VI) is unlikely to create a health hazard at concentrations up to 10 mg Cr(VI)/L. Furthermore, these aerosol measurements may be relevant to estimating airborne exposures to other nonvolatile chemicals.
Finley
B L
BL
McLaren/Hart-ChemRisk, Alameda, California, USA.
Kerger
B D
BD
Dodge
D G
DG
Meyers
S M
SM
Richter
R O
RO
Paustenbach
D J
DJ
D000293:Adolescent; D000328:Adult; D000336:Aerosols; D016902:Air Pollution, Indoor / Q000009:adverse effects / Q000032:analysis*; D002274:Carcinogens, Environmental / Q000008:administration & dosage / Q000009:adverse effects / Q000032:analysis; D002648:Child; D002675:Child, Preschool; D002857:Chromium / Q000008:administration & dosage / Q000009:adverse effects / Q000032:analysis; D004781:Environmental Exposure / Q000009:adverse effects / Q000032:analysis / Q000706:statistics & numerical data; D004784:Environmental Monitoring / Q000295:instrumentation / Q000379:methods; D006794:Household Articles / Q000295:instrumentation*; D006801:Humans; D007223:Infant; D007231:Infant, Newborn; D016018:Least-Squares Analysis; D008875:Middle Aged; D008954:Models, Biological; D018570:Risk Assessment; D014881:Water Supply
D000336:Aerosols; D002274:Carcinogens, Environmental; D002857:Chromium