HPLC of structural isomers with cyclodextrin-poly(vinylamine)-coated silica columns, Part I: Synthesis and characterization of cyclodextrin-bonded stationary phases by NMR solid state.
Different supports for high-performance liquid chromatography are prepared by using the coating technology. These supports are based on silica beads coated with a beta-cyclodextrin-containing poly(vinylamine). Surface area, pore size distribution, and solid-state nuclear magnetic resonance are used for the characterization of these supports. The two different methods of preparation used lead to different arrangements of the polymer layers; hence, the supports have different mobility, rigidity, and accessibility of the cyclodextrin ring.
Crini
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G
Laboratoire de Chimie Macromoléculaire, U.R.A. 351 CNRS, Université des Sciences et Technologies de Lille, Villeneuve d'Ascq, France.
Morcellet
M
M
Torri
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G
D002247:Carbon Isotopes; D002851:Chromatography, High Pressure Liquid / Q000379:methods*; D003505:Cyclodextrins / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008863:Microspheres; D011108:Polymers / Q000737:chemistry*; D011145:Polyvinyls / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry; D013499:Surface Properties
D002247:Carbon Isotopes; D003505:Cyclodextrins; D011108:Polymers; D011145:Polyvinyls; C008996:poly(vinylamine); D012822:Silicon Dioxide