Electron impact mass spectra of some bis-(2-benzothiazolyl)furans and bis-(2-benzothiazolyl)thiophenes.
The electron impact mass spectra of some bis-(2-benzothiazolyl)furans and bis-(2-benzothiazolyl)thiophenes have been recorded and the identity of various ions in the mass spectra established. Compounds 1 and 2 present model substances and it is found that their fragmentation pathway is similar to the mono-(2-benzothiazoles). Compounds where the benzothiazolyl groups are directly substituted on the furan nuclei, but in different positions, exhibit two main pathways of fragmentation: fragmentation of the furan nucleus and fragmentation of the benzothiazole nucleus. Other compounds studied show specific fragmentation characteristic for divinyl furan compounds and for compounds with a phenyl substituent between two heterocyclic nuclei.
Department of Organic Chemistry, Faculty of Chemical Engineering and Technology, University of Zagreb, Croatia.
G
G
Karminski-Zamola
V
V
Tralić-Kulenović
L
L
Fiser-Jakić
M
M
Bajic
D W
DW
Boykin
D005663:Furans / Q000737:chemistry*; D008401:Gas Chromatography-Mass Spectrometry; D013876:Thiophenes / Q000737:chemistry*
D005663:Furans; D013876:Thiophenes