Friedel-Crafts alkylation of benzene and toluene with olefinic C6 hydrocarbons and esters.
To assist our study of the reaction of toluene and other aromatic compounds with methyl oleate and other olefinic esters, benzene and toluene have been alkylated under Friedel-Crafts conditions with hex-1-ene, hex-3-ene, methyl hex-3-enoate and methyl hex-3-enedioate. The products were isolated and identified by NMR and mass spectrometric procedures.
The School of Chemistry, The University of St. Andrews, Fife, UK.
K D
KD
Black
F D
FD
Gunstone
D000475:Alkenes / Q000737:chemistry / Q000378:metabolism*; D001554:Benzene / Q000737:chemistry / Q000378:metabolism*; D055598:Chemical Phenomena; D002621:Chemistry; D006838:Hydrocarbons / Q000737:chemistry / Q000378:metabolism; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D015394:Molecular Structure; D014050:Toluene / Q000378:metabolism*
D000475:Alkenes; D006838:Hydrocarbons; D014050:Toluene; D001554:Benzene