A triphenylboroxin derivative possessing two intramolecular chelates.
Condensation of 2-formylbenzeneboronic acid and 1,1-dimethylhydrazine afforded the title compound, bis(8-B-4)-1,3,5-tris[2-[(N,N-dimethylhydrazono)methyl]-phenyl)]b oroxin, C27H33B3N6O3, a tridehydro cyclic trimer of the expected simple benzaldehyde hydrazone and the first triphenylboroxin derivative found to possess two B chelating interactions. The double chelation induces molecular asymmetry but effects only a slight puckering in the central boroxin ring.
Robinson
P D
PD
Department of Geology, Southern Illinois University, Carbondale 62901-4324, USA. robinson@geo.siu.edu
Groziak
M P
MP
Yi
L
L
D001896:Boron Compounds / Q000737:chemistry*; D002614:Chelating Agents / Q000737:chemistry*; D018360:Crystallography, X-Ray
D001896:Boron Compounds; D002614:Chelating Agents; C103433:bis(8-B-4)-1,3,5-tris(2-((N,N-dimethylhydrazono)methyl)phenyl)boroxin