title: [The determination of toxic compounds with a dinitrophenol structure in the forensic chemical study of cadaveric material].
abstract: A method for forensic chemical assessment of dinitrophenol toxic compounds has been developed. Acetone was used as the isolating agent. The isolates were purified by extraction followed by adsorption in a column packed with silica gel. The analyzed substances are analyzed by chromogenic reactions, from UV and visible spectra in alkali and DMPA, and by thin-layer and high-pressure chromatography. The method allows the detection of 47-83% dinitrophenols in artificial mixtures with liver tissue (with 50 mg of analyzed substance per 100 g of the object). The detection minimum for this group of compounds is 0.5 to 1.0 mg per 100 g of cadaveric material.
authors.forename: V K
authors.initials: VK
authors.lastname: Shormanov
authors.forename: I A
authors.initials: IA
authors.lastname: Fursova
mesh_terms: D002102:Cadaver; D002851:Chromatography, High Pressure Liquid / Q000379:methods; D002855:Chromatography, Thin Layer / Q000379:methods; D004140:Dinitrophenols / Q000032:analysis* / Q000302:isolation & purification; D005554:Forensic Medicine / Q000379:methods*; D006801:Humans; D008099:Liver / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet / Q000379:methods
chemical_list: D004140:Dinitrophenols
vernacular_title: Opredelenie toksicheskikh soedineniĭ dinitrofenol'noĭ struktury pri sudebno-khimicheskom issledovanii trupnogo materiala.