Adsorption from a one-dimensional lattice gas and the Brunauer-Emmett-Teller equation.
An exact treatment of adsorption from a one-dimensional lattice gas is used to eliminate and correct a well-known inconsistency in the Brunauer-Emmett-Teller (B.E.T.) equation-namely, Gibbs excess adsorption is not taken into account and the Gibbs integral diverges at the transition point. However, neither model should be considered realistic for experimental adsorption systems.
Hill
T L
TL
Laboratory of Molecular Biology, National Institute of Diabetes and Digestive and Kidney Diseases, National Institutes of Health, Bethesda, MD 20892, USA.
D005740:Gases / Q000737:chemistry*; D008956:Models, Chemical; D013816:Thermodynamics
D005740:Gases