Quenched molecular reorientation and angular velocity in nanopores.
A theoretical treatment shows how the orientational dependent and spin rotation relaxation rates of a confined nonpolar liquid depend on the average pore size. Experimental nuclear relaxation data on carbon disulfide and cyclohexane in a set of calibrated porous glasses support the theory.
Korb
J P
JP
Laboratoire de Physique de la Matière Condensée, C.N.R.S., Ecole Polytechnique, Palaiseau, France.
Malier
L
L
Cros
F
F
D016880:Anisotropy; D002246:Carbon Disulfide; D003510:Cyclohexanes; D009682:Magnetic Resonance Spectroscopy; D016062:Porosity
D003510:Cyclohexanes; D002246:Carbon Disulfide