(Ethanol)(2,3,7,8,12,13,17,18-octaethylporphinato)manganese(III) perchlorate.
The crystal structure of [Mn(C36H44N4)(C2H6O)]ClO4 has been determined. The average Mn-Np bond distance is 1.997 (5) A and the axial Mn-O bond length is 2.145 (2) A. The manganese(III) ion has a displacement of 0.17 A from the mean plane of the 24-atom porphinato core.
Cheng
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B
Department of Chemistry and Biochemistry, University of Notre Dame, IN 46556, USA.
Scheidt
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WR
D018360:Crystallography, X-Ray; D006863:Hydrogen-Ion Concentration; D008665:Metalloporphyrins / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure
C103292:(ethanol)(2,3,7,8,12,13,17,18-octaethylporphinato)manganese(III) perchlorate; D008665:Metalloporphyrins