title: Factors contributing to the temperature rise during polymerization of resin-modified glass-ionomer cements.
abstract: Part of the setting reaction of a resin-modified glass-ionomer cement (RMGIC) is a photoinitiated polymerization. As a result of the polymerization exotherm, the temperature of the cement may rise during setting. This study investigated the temperature rise for two liner/base- and two restorative-type RMGICs. The effects of factors such as specimen thickness, exposure time and environment temperature were investigated. The thermal diffusivity of the cements was also evaluated. Temperatures were measured using a thermocouple embedded in the centre of 6-mm diameter specimen discs of 1, 2, or 3 mm thickness. The exposure times used to cure the specimens varied from 15 to 60 s. The test were carried out at either 25 or 37 degrees C. The temperature rises attributable to the polymerization reaction ranged from 11 to 26 degrees C for the liner/base cements and from 8 to 17 degrees C for the restorative cements. Increasing the specimen thickness reduced the temperature rise only when inadequate exposure times were used. Raising the environmental temperature resulted in a smaller temperature rise. The thermal diffusivities were determined from cylindrical specimens. These ranged from 1.9 x 10(-3) to 2.5 x 10(-3) cm2 s-1, the lining cements showing lower values than the restorative materials.
authors.affiliation: Biomaterials Department, Eastman Dental Institute, London, UK.
authors.forename: W
authors.initials: W
authors.lastname: Kanchanavasita
authors.forename: G J
authors.initials: GJ
authors.lastname: Pearson
authors.forename: H M
authors.initials: HM
authors.lastname: Anstice
mesh_terms: D055598:Chemical Phenomena; D002627:Chemistry, Physical; D005899:Glass Ionomer Cements / Q000737:chemistry*; D008027:Light; D011108:Polymers / Q000737:chemistry; D019279:Resin Cements / Q000737:chemistry*; D013696:Temperature
chemical_list: D005899:Glass Ionomer Cements; D011108:Polymers; D019279:Resin Cements