Hederagenin glycosides from the flowers of Cephalaria transsylvanica.
Three new triterpenoidal saponins, 3-O-[beta-D-glucopyranosyl(1-->4)-beta-D-Glucopyranosyl(1-->3)-alpha-L- rhamnopyranosyl (1-->4)-beta-D-xylopyranosyl]-hederagenin 28-O-[beta-D-glucopyranosyl (1-->4)-beta-D-glucopyranosyl] ester (1), 3-O-[beta-D-glucopyranosyl (1-->3)-alpha-L-rhamnopyranosyl(1-->2)-beta-D-xylopyranosyl]-hederage nin 28-O-[beta-D-glucopyranosyl(1-->4)-beta-D-glucopyranosyl] ester (2), and 3-O-[alpha-L-rhamnopyranosyl(1-->4)-beta-D-xylopyranosyl]-hederagenin (3) were isolated from the flowers of Cephalaria transsylvanica. Two new prosapogenins, 3-O-[beta-D-glucopyranosyl (1-->4)-beta-D-glucopyranosyl(1-->3)-alpha-L-rhamnopyranosyl(1-->4)- beta-D-xylopyranosyl]-hederagenin (4) and 3-O-[beta-D-glucopyranosyl (1-->3)-alpha-L-rhamnopyranosyl(1-->2)-beta-D-xylopyranosyl]-hederage nin (5) were also isolated after cleavage of the ester-glycosidic linkage of the bisdesmosidic compounds. Structure elucidation was carried out chemically and spectroscopically.
Kirmizigül
S
S
Department of Organic Chemistry, Faculty of Science, Ege University, Izmir, Turkey.
Rose
M E
ME
D009828:Oleanolic Acid / Q000031:analogs & derivatives* / Q000737:chemistry / Q000302:isolation & purification; D010944:Plants / Q000737:chemistry*; D013057:Spectrum Analysis
D009828:Oleanolic Acid; C025763:hederagenin