title: New access to C-disaccharide analogs of alpha, alpha-trehalose using an aqueous hetero Diels-Alder reaction.
abstract: C-disaccharide analogs of trehalose were prepared using an aqueous Diels-Alder reaction as a key step. The resulting major stereoisomer was shown by NMR spectroscopy analysis to have the correct (alpha, alpha') stereochemistry of trehalose.
authors.affiliation: Laboratoire de Chimie Organique Multifonctionnelle, Université de Paris XI, Orsay, France.
authors.forename: A
authors.initials: A
authors.lastname: Lubineau
authors.forename: E
authors.initials: E
authors.lastname: Grand
authors.forename: M C
authors.initials: MC
authors.lastname: Scherrmann
mesh_terms: D002236:Carbohydrate Conformation; D004187:Disaccharides / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008968:Molecular Conformation; D014199:Trehalose / Q000031:analogs & derivatives*
chemical_list: D004187:Disaccharides; D014199:Trehalose