Steroidal alkaloid glycosides from Solanum uporo.
In addition to solamargine, anguivine and isoanguivine, two new steroidal alkaloid glycosides, (23S)-23-hydroxyanguivine and (23S)-23-hydroxyisoanguivine, have been isolated from roots of Solanum uporo, the structures of which have been assigned by comparison with literature data as (23S,25R)-3 beta-[O-alpha-L-rhamnopyranosyl-(1-->2)-O- [beta-D-xylopyranosyl-(1-->3)]-beta-D-glucopyranosyloxy]-22 alpha N-spirosol-5-en-23-ol and (23S,25R)-3 beta-[O-alpha-L-rhamnopyranosyl-(1-->2)-O-[beta-D- xylopyranosyl-(1-->3)]-beta-D-galactopyranosyloxy]-22 alpha N-spirosol-5-en-23-ol.
Ripperger
H
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Institute of Plant Biochemistry, Halle (Saale), Germany.
D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D006027:Glycosides / Q000737:chemistry* / Q000302:isolation & purification; D009682:Magnetic Resonance Spectroscopy; D008969:Molecular Sequence Data; D018517:Plant Roots / Q000737:chemistry*
C104676:23-hydroxyanguivine; C104677:23-hydroxyisoanguivine; D006027:Glycosides