title: Thermodynamics of Formation of Biological Microemulsion (with Cinnamic Alcohol, Aerosol OT, Tween 20, and Water) and Kinetics of Alkaline Fading of Crystal Violet in Them
abstract: The ternary phase diagrams for the formation of biological microemulsions of the combinations CA/AOT/water and CA/Tween 20/water have been presented. The thermodynamics of solution of water in AOT/CA as well as in Tween 20/CA forming w/o microemulsions and solution of oil in Tween 20/water forming o/w microemulsions have been calorimetrically studied. The solution processes are essentially exothermic (with a few exceptions) and have yielded negative entropies, i.e., producing an ordering effect. This has been supported by the measured specific heats of the resulting solution. The pseudo-first-order rate constants (k1) for the alkaline fading of crystal violet in w/o microemulsion medium for the CA/AOT/water and CA/TW 20/water have been found to depend on [water]/[AOT] mole ratio (omega) with maxima at omega = 10. For o/w preparations of CA/TW-20/water, k1 has shown maximum at [CA]/[TW-20] mole ratio omega' = 2, whereas the k2 value has increased with omega'. The salt effect on the reaction has shown significant deviation from expectation in w/o microemulsion. The free energies of activation for the w/o and o/w systems are of the same order, whereas both DeltaHdouble dagger and DeltaSdouble dagger values differ significantly.
authors.affiliation: Department of Chemistry, Jadavpur University, Calcutta, 700032, India
authors.initials: L
authors.lastname: Mukhopadhyay
authors.initials: N
authors.lastname: Mitra
authors.initials: PK
authors.lastname: Bhattacharya
authors.initials: SP
authors.lastname: Moulik