title: Syntheses of spacer-armed carbohydrate components of the Mycobacterium avium serocomplex serovar 8.
abstract: p-Nitrophenyl glycosides of 3-O-Me-beta-D-Glcp-(1-->3)-alpha-L-Rhap, alpha-L-Rhap-(1-->2)-6-deoxy-alpha-L-Talp, and 3-O-Me-beta-D-Glcp-(1-->3)-alpha-L-Rhap-(1-->2)-6-deoxy-alpha-L-++ +Talp have been prepared, related to Mycobacterium avium. Various glycosylation methods have been used for the formation of the interglycosidic linkages. The p-nitrophenyl derivatives were converted into p-isothiocyanatophenyl glycosides, capable of forming neoglycoproteins.
authors.affiliation: Institute of Biochemistry, L. Kossuth University, Debrecen, Hungary.
authors.forename: J
authors.initials: J
authors.lastname: Kerékgyártó
authors.forename: K
authors.initials: K
authors.lastname: Agoston
authors.forename: G
authors.initials: G
authors.lastname: Batta
authors.forename: Z
authors.initials: Z
authors.lastname: Szurmai
mesh_terms: D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D004187:Disaccharides / Q000138:chemical synthesis* / Q000737:chemistry; D006023:Glycoproteins / Q000138:chemical synthesis; D006027:Glycosides / Q000138:chemical synthesis; D006031:Glycosylation; D017879:Isothiocyanates / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008562:Membrane Glycoproteins / Q000737:chemistry; D008969:Molecular Sequence Data; D015269:Mycobacterium avium Complex / Q000737:chemistry*; D009596:Nitrophenols / Q000737:chemistry; D014312:Trisaccharides / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D004187:Disaccharides; D006023:Glycoproteins; D006027:Glycosides; D017879:Isothiocyanates; D008562:Membrane Glycoproteins; D009596:Nitrophenols; D014312:Trisaccharides