New access to C-disaccharide analogs of alpha, alpha-trehalose using an aqueous hetero Diels-Alder reaction.
C-disaccharide analogs of trehalose were prepared using an aqueous Diels-Alder reaction as a key step. The resulting major stereoisomer was shown by NMR spectroscopy analysis to have the correct (alpha, alpha') stereochemistry of trehalose.
Lubineau
A
A
Laboratoire de Chimie Organique Multifonctionnelle, Université de Paris XI, Orsay, France.
Grand
E
E
Scherrmann
M C
MC
D002236:Carbohydrate Conformation; D004187:Disaccharides / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008968:Molecular Conformation; D014199:Trehalose / Q000031:analogs & derivatives*
D004187:Disaccharides; D014199:Trehalose