title: An investigation of the fluidity of concentration polarisation layers in crossflow membrane filtration of an oil-water emulsion using chemical shift selective flow imaging.
abstract: A chemical shift selective NMR flow imaging sequence using stimulated echoes for data acquisition is presented. The sequence was tested using a 20% (vol/vol) oil-water emulsion formed from a soluble cutting oil, which was passed through a simple flow phantom to yield two-dimensional velocity distribution maps of the oil droplets and of the water separately. It was then used to investigate the fluidity of concentration polarisation layers formed from the oil droplets during crossflow membrane filtration of a 5% (vol/vol) emulsion of the same cutting oil. A simple membrane filtration module was used for this purpose, with the feedstock emulsion fed into the lumen of a single tubular membrane at a trans-membrane pressure difference P approximately 70 kPa and crossflow Reynolds number, Re, in the range 100-1000. The results confirm a net axial flow rate < 7.5 microns/s (half digital resolution in the velocity dimension) for the oil polarisation layer. Under these conditions, the upper limit for oil flow tangential to the membrane in the polarised layer is less than 15% of the convective flow of oil towards the membrane.
authors.affiliation: School of Physics, University of New South Wales, Sydney, Australia.
authors.forename: S
authors.initials: S
authors.lastname: Yao
authors.forename: A G
authors.initials: AG
authors.lastname: Fane
authors.forename: J M
authors.initials: JM
authors.lastname: Pope
mesh_terms: D004655:Emulsions; D005374:Filtration; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008560:Membrane Fluidity; D008567:Membranes, Artificial; D009821:Oils; D019047:Phantoms, Imaging; D014867:Water
chemical_list: D004655:Emulsions; D008567:Membranes, Artificial; D009821:Oils; D014867:Water