title: Capillary electrophoresis of organotin compounds with indirect UV detection.
abstract: A capillary electrophoresis (CE)-indirect UV absorbance detection method for organotin compounds is described. The five triorganotin cations, viz., trimethyltin (TMT), triethyltin (TET), tripropyltin (TPT), tributyltin (TBT) and triphenyltin (TPhT), were efficiently separated by CE in 10 min with a 5 mM acetate buffer (pH 4.5) containing 3 mM 4-aminopyridine (4-AP). 4-AP also functioned as a UV-absorbing coion for the indirect detection of these UV-transparent organotin species. Simultaneous separation of di- and triorganotins was achieved with the addition of alpha-cyclodextrin (alpha-CD) as a modifier in the electrophoresis buffer. Linearity (r > or = 0.995) of about two orders of magnitude was generally obtained. The concentration limits of detection for the organotin compounds studied were between 2 and 20 microM (as tin). The relative standard deviation (RSD) values were in the range 1.3-7.1%. The applicability of the method for the analysis of marine sediment was examined.
authors.affiliation: Department of Chemistry, Tunghai University, Taichung, Taiwan.
authors.forename: K S
authors.initials: KS
authors.lastname: Whang
authors.forename: C W
authors.initials: CW
authors.lastname: Whang
mesh_terms: D002138:Calibration; D019075:Electrophoresis, Capillary; D009947:Organotin Compounds / Q000032:analysis*; D014220:Trialkyltin Compounds / Q000032:analysis; D014267:Triethyltin Compounds / Q000032:analysis; D014298:Trimethyltin Compounds / Q000032:analysis; D014466:Ultraviolet Rays; D014874:Water Pollutants, Chemical / Q000032:analysis
chemical_list: D009947:Organotin Compounds; D014220:Trialkyltin Compounds; D014267:Triethyltin Compounds; D014298:Trimethyltin Compounds; D014874:Water Pollutants, Chemical; C046488:trimethyltin; C011559:tributyltin; C031575:triethyltin; C030665:triphenyltin