1,8-bis(hydroxymethyl)anthracene.
Anthracene-1,8-dimethanol, C16H14O2, crystallized in the centrosymmetric space group P21/n. The anthracene core is nearly planar and shows good agreement with the anthracene core of anthracene-1,8-dicarboxylic acid. The geometric disposition of the hydroxymethyl groups and the values of the hydrogen-bond parameters are strikingly similar to those in the naphthalene analog. As in that structure, each hydroxyl group participates both as a donor and acceptor in an infinite zigzag chain of hydrogen bonds which propagates along the [010] direction. Moreover, the disposition of the entire molecule in the cell of the present compound is also strikingly similar to that of the naphthalene analog in its cell.
Aumiller
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WD
Department of Chemistry, Ohio State University, Columbus 43210, USA.
Gerkin
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RE
D000873:Anthracenes / Q000737:chemistry*; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D000432:Methanol / Q000031:analogs & derivatives* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure
D000873:Anthracenes; C106964:anthracene-1,8-dimethanol; D000432:Methanol