Symmetry Analysis of the Vibrational Dynamics of the H3 D2 + and H2 D3 + Complexes
A symmetry analysis of the H3 D2 + and H2 D3 + complexes in a model with one large amplitude motion, the propeller-like internal rotation, is presented. Symmetry coordinates and symmetry adapted polynomial expansions of the potential, dipole moment, and polarizability functions are derived within the framework of the extended molecular symmetry group G 3 (2, 2) using the projection operator and Molien function techniques.
Soldan
P
J. Heyrovsky Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejskova 3, Prague 8, 182 23, Czech Republic
spirko
V
Kraemer
WP