A new entry to glycosylamines.
A new procedure for the introduction of a nitrogen atom into the anomeric centre leading to glycosylamines is described. The new reaction consisting of the condensation of a furanose with a hydroxylamine in the presence of a Lewis acid occurs with a complete degree of diastereoselectivity.
Merchán
F L
FL
Departamento de Química Orgánica, ICMA, Universidad de Zaragoza, Spain.
Merino
P
P
Tejero
T
T
D005944:Glucosamine / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry; D013237:Stereoisomerism
D005944:Glucosamine; D009584:Nitrogen