title: Dephosphorylation and benzoylation reactions occurring in the benzoolysis of diacyl-, alkylacyl-, alk-1-enylacyl-, and acyl-lyso-glycerophosphocholines.
abstract: Series of benzoolysis experiments with 1,2-dipalmitoyl glycerophosphocholine (GPC), 1-palmitoyl-2-lyso GPC, and 1-O-hexadecenyl-2-oleoyl GPC, as well as a few experiments with 1-oleoyl-2-acetyl GPC and 1-O-hexadecyl-2-acetyl GPC are reported. The results are used to present a consistent picture of the various dephosphorylation and benzoylation reactions occurring in molten benzoic anhydride.
authors.affiliation: Department of Analytical Chemistry, Utrecht University, The Netherlands.
authors.forename: W J
authors.initials: WJ
authors.lastname: Gelsema
authors.forename: H
authors.initials: H
authors.lastname: van den Bosch
mesh_terms: D000215:Acylation; D000478:Alkylation; D001554:Benzene / Q000737:chemistry; D001565:Benzoates; D005997:Glycerylphosphorylcholine / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry; D008956:Models, Chemical; D010713:Phosphatidylcholines / Q000138:chemical synthesis* / Q000737:chemistry; D010766:Phosphorylation
chemical_list: D001565:Benzoates; D010713:Phosphatidylcholines; D005997:Glycerylphosphorylcholine; C102988:benzoic anhydride; D001554:Benzene