title: Identification of the absolute configuration of pectenotoxin-6, a polyether macrolide compound, by NMR spectroscopic method using a chiral anisotropic reagent, phenylglycine methyl ester.
abstract: The absolute configuration of pectenotoxin-6 (4, PTX6), found in association with diarrhetic shellfish poisoning, was identified by NMR spectroscopy using a chiral anisotropic reagent, phenylglycine methyl ester (PGME), which was condensed with a carboxyl group of 4.
authors.affiliation: Faculty of Agriculture, Tohoku University, Sendai, Japan.
authors.forename: K
authors.initials: K
authors.lastname: Sasaki
authors.forename: M
authors.initials: M
authors.lastname: Satake
authors.forename: T
authors.initials: T
authors.lastname: Yasumoto
mesh_terms: D005663:Furans / Q000737:chemistry*; D005998:Glycine / Q000031:analogs & derivatives; D018942:Macrolides; D009682:Magnetic Resonance Spectroscopy; D008387:Marine Toxins / Q000737:chemistry*; D011714:Pyrans / Q000737:chemistry*; D013237:Stereoisomerism; D000095702:Polyether Toxins
chemical_list: D005663:Furans; D005998:Glycine; D018942:Macrolides; D008387:Marine Toxins; D011714:Pyrans; C114399:pectenotoxin 6; D000095702:Polyether Toxins; C033393:methyl phenylglycine