Coherence sidebands in adiabatic decoupling
RF pulse sequences applied to IS spin systems may produce substantial transverse antiphase S magnetization coupled to antiphase I magnetization, just prior to detection of the S signal, for samples containing a range of J coupling constants, or when pulse sequence delays are misset from ideal values. This magnetization is generally considered to be unobservable. Adiabatic decoupling on the I spins during signal detection efficiently converts this magnetization to observable S signal in the form of sidebands which we dub "coherence sidebands." Three single-transient pulsed-field-gradient methods are described for eliminating these unwanted sidebands. The techniques are applicable to 1H-detected 13C-decoupled experiments on spectrometers operating at a 1H frequency of up to 2 GHz. Copyright 1997 Academic Press. Copyright 1997Academic Press
Bendall
MR
School of Molecular Sciences, James Cook University of North Queensland, Townsville, Queensland, 4811, Australia.
Skinner
TE