Dangling bond dynamics on the silicon (100)-2x1 surface: dissociation, diffusion, and recombination
The dynamics of dangling bond (DB) diffusion was studied after deuterium desorption from the silicon (100)-2x1 surface. At elevated temperatures, paired DB sites produced after desorption unpaired as deuterium atoms hopped from adjacent dimers. Below 620 kelvin, the unpaired configuration most commonly observed corresponded to two DBs on adjacent silicon dimers. At higher temperatures, unpaired DBs executed one-dimensional walks along the dimer rows, and recombination was observed with the same partner after walks lasting many minutes. The frequency and extent of these excursions increased with temperature. Above 660 kelvin, complete dissociation was observed and was sometimes followed by recombination by means of partner exchange. The implications for low-temperature materials growth are discussed.
McEllistrem
M
Venable and Kenan Laboratories, Department of Chemistry, University of North Carolina, Chapel Hill, NC 27599-3290, USA.
Allgeier
M
Boland
JJ