title: Novel preconcentration technique for on-line coupling to high-speed narrow-bore capillary gas chromatography: sample enrichment by equilibrium (ab)sorption. II. Coupling to a portable micro gas chromatograph.
abstract: The technique of equilibrium (ab)sorption has been proven to be a powerful method for preconcentration of gaseous samples for high-speed narrow-bore capillary gas chromatography (GC) in general and field-portable GC instruments, often referred as micro GCs, in particular. Using a simple experimental set-up equipped with an open-tubular enrichment column it is possible to produce a homogeneously enriched sample plug, allowing reproducible injections of an enriched sample into the micro GC. Using a non-polar trapping column enrichment factors found for n-alkanes in the range of C7 to C10 ranged from 15 to 150 and agree well with calculated values. Using a highly retentive Thermocap column, the enrichment factor observed for heptane was above 500. As the use of this new preconcentration method requires only minimum modification of the micro GC, the chromatographic performance of the instrument was not compromised by direct coupling to the preconcentration device. Examples of on-line enrichment with portable micro GC analysis of VOCs from air are shown. These examples clearly demonstrate the potentials of the new method in field analysis.
authors.affiliation: Eindhoven University of Technology, Laboratory of Instrumental Analysis, Netherlands.
authors.forename: H P
authors.initials: HP
authors.lastname: Tuan
authors.forename: H G
authors.initials: HG
authors.lastname: Janssen
authors.forename: C A
authors.initials: CA
authors.lastname: Cramers
authors.forename: P
authors.initials: P
authors.lastname: Mussche
authors.forename: J
authors.initials: J
authors.lastname: Lips
authors.forename: N
authors.initials: N
authors.lastname: Wilson
authors.forename: A
authors.initials: A
authors.lastname: Handley
mesh_terms: D000042:Absorption; D000473:Alkanes / Q000032:analysis* / Q000737:chemistry; D001554:Benzene / Q000032:analysis* / Q000737:chemistry; D002849:Chromatography, Gas / Q000295:instrumentation / Q000379:methods*; D006536:Heptanes / Q000032:analysis / Q000737:chemistry; D009862:Online Systems; D010420:Pentanes / Q000032:analysis / Q000737:chemistry; D013997:Time Factors; D014050:Toluene / Q000032:analysis* / Q000737:chemistry; D014835:Volatilization
chemical_list: D000473:Alkanes; D006536:Heptanes; D010420:Pentanes; D014050:Toluene; C028618:n-heptane; C033353:pentane; D001554:Benzene