High-Resolution Fourier Transform Infrared Spectroscopy of Nitrosyl Fluoride
The high-resolution FTIR spectrum of FNO has been recorded and the rovibrational structure of the essentially unperturbed nu3, 2nu3, and nu1 + nu3 cold bands and the 2nu3 <-- nu3, nu2 + nu3 <-- nu3, and nu1 + nu2 + nu3 <-- nu3 hot bands has been analyzed. The perturbed bands nu1 and nu1 + nu2 have been assigned and the data analyzed by fitting the transitions with the dark states nu2 + 2nu3 and 2nu2 + 2nu3. Parameters for both light and dark states together with Coriolis coupling parameters have been determined. Copyright 1998 Academic Press. Copyright 1998Academic Press
Evans
CJ
Department of Chemistry, Monash University, Clayton, Vic, 3168, Australia
McNaughton
D
Dexter
P
Lawrance
W