A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods
An unusual luminescent inorganic oxide, Sr2CeO4, was identified by parallel screening techniques from within a combinatorial library of more than 25,000 members prepared by automated thin-film synthesis. A bulk sample of single-phase Sr2CeO4 was prepared, and its structure, determined from powder x-ray diffraction data, reveals one-dimensional chains of edge-sharing CeO6 octahedra, with two terminal oxygen atoms per cerium center, that are isolated from one another by Sr2+ cations. The emission maximum at 485 nanometers appears blue-white and has a quantum yield of 0.48 +/- 0.02. The excited-state lifetime, electron spin resonance, magnetic susceptibility, and structural data all suggest that luminescence originates from a ligand-to-metal Ce4+ charge transfer.
Danielson
E
Symyx Technologies, 3100 Central Expressway, Santa Clara, CA 95051, USA. The authors all contributed equally to this work.
Devenney
M
Giaquinta
DM
Golden
JH
Haushalter
RC
McFarland
EW
Poojary
DM
Reaves
CM
Weinberg
WH
Wu
XD