title: 23Na chemical shifts and local structure in crystalline, glassy, and molten sodium borates and germanates.
abstract: A simple correlation between average Na-O bond length and 23Na isotropic chemical shift in crystalline germanates and borates has been established, similar to existing correlations for sodium in silicates and carbonates. This empirical trend is discussed in terms of a decreasing paramagnetic contribution to the chemical shift with increasing average bond length. The correlation is then applied to data for sodium borate and germanate glasses and melts from room temperature to 1200 degrees C, where both structural and compositional effects on the chemical shift are apparent.
authors.affiliation: Department of Geological and Environmental Sciences, Stanford University, CA 94305-2115, USA.
authors.forename: A M
authors.initials: AM
authors.lastname: George
authors.forename: S
authors.initials: S
authors.lastname: Sen
authors.forename: J F
authors.initials: JF
authors.lastname: Stebbins
mesh_terms: D001881:Borates / Q000737:chemistry*; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D003460:Crystallization; D005857:Germanium / Q000737:chemistry*; D005898:Glass / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D012975:Sodium Isotopes
chemical_list: D001881:Borates; D012975:Sodium Isotopes; D005857:Germanium; C040516:germanium oxide; C010634:sodium borate