[Reactions of 1-(X-benzoyl)-4-R-thiosemicarbazide with chloroacetone and omega-bromoacetophenone. V. 4-(o-tolyl)-thiosemicarbazide of of o-chloro- and p-chlorobenzoic acid].
The reactions of 4-(o-tolyl)-thiosemicarbazide of o-chloro- and p-chlorobenzoic acid (Ii, j) with chloroacetone and omega-bromoacetophenone were investigated in: methanolic medium (method D); methanolic medium in the presence of anhydrous CH3COONa (method E); methanolic medium in the presence of N(C2H5)3 (method F). The properties of compounds II p-t and III p-t were determined under the conditions of basic and acidic hydrolysis. The results of UV, IR and NMR spectroscopic measurements were reported.
Bielak
E
E
Katedra i Zakład Chemii Ogólnej Akademii Medycznej w Lublinie.
Biliński
S
S
D000096:Acetone / Q000031:analogs & derivatives* / Q000737:chemistry; D000098:Acetophenones / Q000737:chemistry*; D002723:Chlorobenzoates / Q000737:chemistry*; D006868:Hydrolysis; D009682:Magnetic Resonance Spectroscopy; D000432:Methanol / Q000737:chemistry; D012663:Semicarbazides / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D019265:Spectroscopy, Near-Infrared
D000098:Acetophenones; D002723:Chlorobenzoates; D012663:Semicarbazides; D000096:Acetone; C005151:thiosemicarbazide; C006973:chloroacetone; C013190:phenacyl bromide; D000432:Methanol
Reakcje 1-(X-benzoilo)-4-R-tiosemikarbazydu z chloroacetonem i omega-bromoacetofenonem. V. 4-(o-tolilo)-tiosemikarbazyd kwasu o-chloro-i p-chlorobenzoesowego.