title: Assessment of the insecticide carbofuran's potential to contaminate groundwater through soils in the subtropics.
abstract: The possible contamination of groundwater by the insecticide carbofuran was assessed with the behavior assessment model (BAM) and groundwater pollution-potential model (GWP). Dissipation coefficients of this insecticide in two subtropical soils at different moisture contents and soil temperatures were studied by determining the degradation and adsorption of the herbicide in soils. Movement of carbofuran was studied by leaching the insecticide in a soil column in the laboratory. Under 40% field capacity and at 25 degrees C, more than 80% of carbofuran residue was found in both Luchu clay and Yuanlin silty clay loam after incubation for 63 days. The results indicate that the higher the moisture content in the soil, the less the carbofuran residue under the soil moisture below the field capacity. Carbofuran tends to dissipate more easily in Yuanlin soil than in Luchu soil. The distribution coefficient (Kd) with r2 of 0.69 and 0.92 for Luchu and Yuanlin soils, respectively, was found using the first-order kinetics law. In leaching experiment, carbofuran exhibited easier movement in Luchu than in Yuanlin soil.
authors.affiliation: Department of Agricultural Chemistry, National Taiwan University, Taipei, Taiwan.
authors.forename: J H
authors.initials: JH
authors.lastname: Yen
authors.forename: F L
authors.initials: FL
authors.lastname: Hsiao
authors.forename: Y S
authors.initials: YS
authors.lastname: Wang
mesh_terms: D002235:Carbofuran / Q000032:analysis*; D004784:Environmental Monitoring; D005618:Fresh Water / Q000032:analysis*; D007306:Insecticides / Q000032:analysis*; D012989:Soil Pollutants / Q000032:analysis*; D013624:Taiwan; D013696:Temperature; D014329:Tropical Climate; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D007306:Insecticides; D012989:Soil Pollutants; D014874:Water Pollutants, Chemical; D002235:Carbofuran