title: [Reactions of 1-(X-benzoyl)-4R-thiosemicarbazide with chloroacetone and omega-bromoacetophenone. IV. 4-phenyl and 4-(p-tolyl)-thiosemicarbazide of o-chlorobenzoic acid].
abstract: The reactions of 4-phenyl and 4-(p-tolyl)-thiosemicarbazide of o-chlorobenzoic acid (Ig, h) with chloroacetone and omega-bromoacetophenone were investigated in: methanolic medium (method D); methanolic medium in the presence of anhydrous CH3COONa (method E); methanolic medium in the presence of N(C2H5)3 (method F). In the methods E and F mercaptotriazoles Vg, h were obtained. The properties of compounds II ł-o and III ł-o were determined under the conditions of basic and acidic hydrolysis. The results of UV, IR and NMR spectroscopic measurements were reported.
authors.affiliation: Katedra i Zakład Chemii Ogólnej Akademii Medycznej w Lublinie.
authors.forename: E
authors.initials: E
authors.lastname: Bielak
authors.forename: S
authors.initials: S
authors.lastname: Biliński
mesh_terms: D000096:Acetone / Q000031:analogs & derivatives* / Q000737:chemistry; D000098:Acetophenones / Q000737:chemistry*; D002723:Chlorobenzoates / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D000432:Methanol / Q000737:chemistry; D012663:Semicarbazides / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D019265:Spectroscopy, Near-Infrared
chemical_list: D000098:Acetophenones; D002723:Chlorobenzoates; D012663:Semicarbazides; D000096:Acetone; C005151:thiosemicarbazide; C006973:chloroacetone; C013190:phenacyl bromide; D000432:Methanol
vernacular_title: Reakcje 1-(X-benzoilo)-4-R-tiosemikarbazydu z chloroacetonem i omega-bromoacetofenonem. IV. 4-fenylo- i 4-(p-tolilo)-tiosemikarbazyd kwasu o-chlorobenzoesowego.