[Reactions of 1-(X-benzoyl)-4-R-thiosemicarbazide with chloroacetone and omega-bromoacetophenone. VI. 4-(o-tolyl)-thiosemicarbazide of o-nitro - and p-nitrobenzoic acid].
The reactions of 4-(o-tolyl)-thiosemicarbazide of o-nitro- and p-nitrobenzoic acid (Ik, l) with chloroacetone and omega-bromoacetophenone were investigated in: methanolic medium (method D); methanolic medium in the presence of anhydrous CH3COONa (method E); methanolic medium in the presence of N(C2H5)3 (method F). The properties of compounds IIu-y and IIIu-y were determined under the conditions of basic and acidic hydrolysis. The results of UV, IR and NMR spectroscopic measurements were reported.
Bielak
E
E
Katedra i Zakład Chemii Ogólnej Akademii Medycznej w Lublinie.
Biliński
S
S
D000096:Acetone / Q000031:analogs & derivatives* / Q000737:chemistry; D000098:Acetophenones / Q000737:chemistry*; D000900:Anti-Bacterial Agents / Q000138:chemical synthesis* / Q000737:chemistry; D001419:Bacteria / Q000187:drug effects; D006090:Gram-Negative Bacteria / Q000187:drug effects; D006094:Gram-Positive Bacteria / Q000187:drug effects; D006868:Hydrolysis; D009682:Magnetic Resonance Spectroscopy; D000432:Methanol / Q000737:chemistry; D009579:Nitrobenzoates / Q000737:chemistry*; D012663:Semicarbazides / Q000737:chemistry*; D013045:Species Specificity; D013056:Spectrophotometry, Ultraviolet; D019265:Spectroscopy, Near-Infrared
D000098:Acetophenones; D000900:Anti-Bacterial Agents; D009579:Nitrobenzoates; D012663:Semicarbazides; D000096:Acetone; C005151:thiosemicarbazide; C006973:chloroacetone; C013190:phenacyl bromide; D000432:Methanol
Reakcje 1-(X-benzoilo)-4-R-tiosemikarbazydu z chloroacetonem i omega-bromoacetofenonem. VI. 4-(o-tolilo)-tiosemikarbazyd kwasu o-nitro- i p-nitrobenzoesowego.