A 2-alkyl substituted 2,3,1-benzodiazaborine.
The structure of the fourth member of a family of structurally related 2,3,1-benzodiheteroborines has been solved by crystallographic means, providing data for proper direct comparison with the others. The title compound, 1,2-dihydro-1-hydroxy-2-methyl-2,3,1-benzodiazaborine (C8H9BN2O) is obtained via condensation of 2-formylbenzeneboronic acid and methylhydrazine, and is similar in most respects to its 2-unsubstituted parent, in internal geometry and intramolecular association topography, but has some subtle oxazaborine-like characteristics.
Robinson
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PD
Department of Geology, Southern Illinois University, Carbondale 62901-4324, USA. robinson@geo.siu.edu
Groziak
M P
MP
Chen
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L
D001372:Aza Compounds / Q000737:chemistry*; D001896:Boron Compounds / Q000737:chemistry*; D018360:Crystallography, X-Ray; D015394:Molecular Structure
C111006:1,2-dihydro-1-hydroxy-2-methyl-2,3,1-benzodiazaborine; D001372:Aza Compounds; D001896:Boron Compounds