Penetration of household insecticides through different types of textile fabrics.
Six different types of fabrics were compared for their ability to protect against human exposure to three different commercial household aerosol insecticides. Fabrics used in this investigation were, 100% cotton, cotton-polyester thermal underwear, cotton-polyester blend (twill), 100% acrylic, 100% wool and artificial silk (rayon). The household insecticides were, Black Flag (Ant and Roach Killer), Raid (Ant and Roach Killer) and Hot Shot (Wasp and Hornet Killer) containing propoxur, permethrin/pyrethrins and chlorpyrifos/allethrins as their active ingredients respectively. A fluorescent tracer, 4-methyl-7-diethyl amino coumarin was mixed with the aerosol (or equivalent aliquot) and sprayed onto cloth squares fitted on Whatman paper patches. The percentage of penetration through the cloth was quantified by the intensity of the fluorescence spectrum of each patch extract and the amount of the tracer recovered was calculated. The extract was concentrated to 1/10th of the volume to measure the content of each of the insecticides by supercritical fluid chromatography (SFC) using electron capture (ECD) and diode array detectors. Scanning electron microscope (SEM) images of the fabrics showed the geometry of the yarn. The results obtained from the fluorescence spectra, SFC and SEM showed that cotton-polyester (twill), cotton, wool and cotton thermal underwear were the least penetrable materials for the aerosols. On the other hand, acrylic and artificial silk (rayon) were the most penetrable cloth types.
Saleh
M A
MA
Department of Chemistry, Texas Southern University, Houston 77004, USA.
Kamel
A
A
el-Demerdash
A
A
Jones
J
J
D000336:Aerosols; D000818:Animals; D002482:Cellulose; D003374:Coumarins / Q000032:analysis; D005456:Fluorescent Dyes / Q000032:analysis; D003368:Gossypium; D007306:Insecticides / Q000032:analysis*; D008855:Microscopy, Electron, Scanning; D010539:Permeability; D011091:Polyesters; D011481:Protective Clothing; D013784:Textiles / Q000032:analysis*; D014935:Wool
D000336:Aerosols; D003374:Coumarins; D005456:Fluorescent Dyes; D007306:Insecticides; D011091:Polyesters; D002482:Cellulose; C002166:4-methyl-7-diethylaminocoumarin; C012024:rayon, purified