Diode Laser Spectroscopy of the nu1 and nu3 Bands of SD+3
The nu1 and nu3 bands of SD+3 were observed at 5.45 µm with a diode laser spectrometer. The ions were generated in a concentration-modulated, low-temperature, hollow-cathode discharge of deuterium and carbonyl sulfide gases. One hundred and ninety-two lines were measured and assigned to SD+3. The majority of these lines were assigned to the nu3 perpendicular band with 49 lines assigned to the nu1 parallel band. A simultaneous fit of these bands provided the first experimental parameters for the SD+3 ion. Copyright 1998 Academic Press.
Xia
C
Department of Chemistry, Mississippi State University, Mississippi State, Mississippi, 39762-9573
Sanz
MM
Foster
SC