title: Effects of radical polymerizable spirocyclic monomers with new polymerization initiator systems on adhesion.
abstract: To develop a non-polymerization shrinkage adhesive resin, the effects of the contents varying 0-20 wt% radical polymerizable spirocyclic monomers of 2-methylene-1, 4, 6-trioxyaspiro [4, 6] undecane (MTSU) and 2-methylene-8, 9-benzo-1, 4, 6 trioxyaspiro [4, 4] nonane (BTSN) together with three kinds of initiator systems in adhesive resin on bonding to both Ni-Cr alloy and unetched enamel were investigated. Tensile bond strength to either Ni-Cr alloy or unetched enamel was affected by the inclusion of MTSU or BTSN, and indicated that increased contents of MTSU or BTSN resulted in decreased bond strength to the metal in the negative correlations. Regarding the bond strength to Ni-Cr alloy, however, the effective concentration of BTSN was found to be 5 wt%, and the mean bond strength was 58.5 and 58.6 MPa, respectively. The data of differential scanning calorimeter measurement, on the other hand, showed that the copolymerization of MTSU with conventional methacrylate monomers was not completely achieved.
authors.affiliation: Department of Research and Development, Shofu Inc., Kyoto, Japan.
authors.forename: K
authors.initials: K
authors.lastname: Ikemura
authors.forename: K
authors.initials: K
authors.lastname: Arai
authors.forename: T
authors.initials: T
authors.lastname: Endo
authors.forename: T
authors.initials: T
authors.lastname: Kawakami
authors.forename: H
authors.initials: H
authors.lastname: Hashimoto
mesh_terms: D000268:Adhesiveness; D000704:Analysis of Variance; D000818:Animals; D002417:Cattle; D002858:Chromium Alloys; D003188:Composite Resins / Q000737:chemistry*; D001840:Dental Bonding; D008422:Materials Testing; D011108:Polymers / Q000737:chemistry; D019279:Resin Cements / Q000737:chemistry*; D013141:Spiro Compounds / Q000737:chemistry*; D013718:Tensile Strength
chemical_list: C111564:2-methylene-1,4,6-trioxyspiro(4,6)undecane; C111563:2-methylene-8,9-benzo-1,4,6-trioxyspiro(4,4)nonane; D002858:Chromium Alloys; D003188:Composite Resins; D011108:Polymers; D019279:Resin Cements; D013141:Spiro Compounds