title: 14N Hyperfine Structure in the Pure Rotational Spectrum of 24Mg14N12C
abstract: The pure rotational spectrum of 24Mg14N12C, between 11.9 and 23.9 GHz, has been measured using a pulsed jet Fourier transform microwave spectrometer. The hyperfine structure due to the 14N nucleus has been measured, and the nuclear quadrupole coupling, Fermi contact, and dipole-dipole interaction constants have been determined. The ionic character of the metal-isocyanide bond has been investigated through the nuclear quadrupole and magnetic hyperfine parameters. Copyright 1998 Academic Press.
authors.affiliation: Department of Chemistry, The University of British Columbia, 2036 Main Mall, Vancouver, B.C., V6T 1Z1, Canada
authors.initials: KA
authors.lastname: Walker
authors.initials: MCL
authors.lastname: Gerry