Pseudopterane and norcembrane diterpenoids from the Caribbean sea plume Pseudopterogorgia acerosa.
A chemical study of the common Caribbean sea plume Pseudopterogorgia acerosa from Puerto Rico has produced two previously undescribed secondary metabolites. One of them, 1, is a new representative of the pseudopterane family of diterpenes possessing the uncommon 3,4;5,6 diepoxyfuran moiety. The other metabolite, 2, is a rare norcembranolide diterpene. Their chemical structures, including relative stereochemistry, were established by detailed analysis of the spectral data in addition to NMR spectral comparisons with known pseudopterane and cembrane models.
Rodríguez
A D
AD
Department of Chemistry, University of Puerto Rico, Río Piedras 00931-3346, USA. abrodrig@upracd.upr.clu.edu
Soto
J J
JJ
D000818:Animals; D002240:Carbohydrate Sequence; D017691:Caribbean Region; D003063:Cnidaria / Q000737:chemistry*; D004224:Diterpenes / Q000032:analysis / Q000302:isolation & purification*; D009682:Magnetic Resonance Spectroscopy; D008969:Molecular Sequence Data
D004224:Diterpenes