title: Sensitivity of Saturation Transfer Electron Spin Resonance Extended to Extremely Slow Mobility in Glassy Materials
abstract: A novel extension of the saturation transfer (ST) ESR technique that enables the determination of extremely long rotational correlation times of nitroxide spin labels up to values around 10(4) s is proposed. The method is based on the observation that the integral of ST-ESR spectra is sensitive to the spin-lattice relaxation time of the electron of the spin label, which in turn is directly dependent upon the rotational correlation time. The method is applied to the spin label TEMPOL (4-hydroxy-2,2,6,6-tetramethylpiperidine-N-oxyl) in glycerol. From the known viscosity data and the related rotational correlation times of the TEMPOL spin label in glycerol, the rotational correlation times of unknown samples can be determined. The method is especially applicable to systems with a very high viscosity, such as glassy materials. The method is applied to a 20 wt% glucose-water mixture in the glassy state, giving a value for the highest limiting rotational correlation time of about 10(3) s at a temperature of 45 K below the glass transition temperature of this system. This is an extension by six decades for the rotational correlation time, as compared to the current application of ST-ESR. Copyright 1998 Academic Press.
authors.affiliation: Food Physics Group, Wageningen Agricultural University, Wageningen, 6700 EV, The Netherlands
authors.lastname: van den Dries IJ
authors.lastname: de Jager PA
authors.initials: MA
authors.lastname: Hemminga