title: Effects of aminobenzoic acid derivatives with 4-AET/HEMA in self-etching primer on bonding to ground dentin.
abstract: The effect of the inclusion of aminobenzoic acid derivatives (ABAD) in a self-etching primer comprising 4-acryloxyethyltrimellitic acid (4-AET), HEMA and water on shear bond strength to ground dentin was investigated. The mean bond strengths to dentin were significantly increased by the inclusion of 0.307 mol% ABAD in the 4-AET/HEMA primer, when compared with the control (0 wt% ABAD) (p < 0.01). A particularly high value (38.0 MPa) of shear bond strength was obtained in the use of the primer containing p-nitroanthranilic acid (p-NAA). It seemed to assume that the effect of p-NAA could be caused by the strong electron-withdrawing group of -NO2. From SEM observation, it was found that bonding resin appeared to adhere strongly to the ground dentin without formation of any resin-tags in the dentinal tubules. It was thought that the ABAD with 4-AET/HEMA could perform facilitating photo-polymerization at the bonding interface, and resulted in increased bond strength to ground dentin, and that the bond strength could be affected by the electronegativities of substitutional groups of ABAD.
authors.affiliation: Department of Research and Development, Shofu Inc., Kyoto, Japan.
authors.forename: K
authors.initials: K
authors.lastname: Ikemura
authors.forename: K
authors.initials: K
authors.lastname: Arai
authors.forename: H
authors.initials: H
authors.lastname: Hashimoto
authors.forename: T
authors.initials: T
authors.lastname: Kawakami
mesh_terms: D010129:4-Aminobenzoic Acid / Q000737:chemistry*; D000704:Analysis of Variance; D000818:Animals; D002417:Cattle; D001840:Dental Bonding; D017220:Dentin-Bonding Agents / Q000737:chemistry*; D008422:Materials Testing; D008689:Methacrylates; D008855:Microscopy, Electron, Scanning; D014233:Tricarboxylic Acids / Q000737:chemistry*; D062367:ortho-Aminobenzoates / Q000737:chemistry; D062366:para-Aminobenzoates
chemical_list: C111562:4-acryloxyethyltrimellitic acid; D017220:Dentin-Bonding Agents; D008689:Methacrylates; D014233:Tricarboxylic Acids; D062367:ortho-Aminobenzoates; D062366:para-Aminobenzoates; C031385:anthranilic acid; C005044:hydroxyethyl methacrylate; D010129:4-Aminobenzoic Acid