14N Hyperfine Structure in the Pure Rotational Spectrum of 24Mg14N12C
The pure rotational spectrum of 24Mg14N12C, between 11.9 and 23.9 GHz, has been measured using a pulsed jet Fourier transform microwave spectrometer. The hyperfine structure due to the 14N nucleus has been measured, and the nuclear quadrupole coupling, Fermi contact, and dipole-dipole interaction constants have been determined. The ionic character of the metal-isocyanide bond has been investigated through the nuclear quadrupole and magnetic hyperfine parameters. Copyright 1998 Academic Press.
Walker
KA
Department of Chemistry, The University of British Columbia, 2036 Main Mall, Vancouver, B.C., V6T 1Z1, Canada
Gerry
MCL