Studies on the constituents of Calliandra anomala (Kunth) Macbr. IV. Structure analysis by HPLC retention time and FAB-MS spectrum.
Three new triterpenoidal saponins were isolated from the branches of Calliandra anomala (KUNTH) MACBR. On elucidation of their structures, we noticed correlations between a series of structures and their HPLC retention time. By this behavior and the FAB-MS spectrum, the structures of three saponins (calliandra saponin M, N and O) were established.
Tani
C
C
Kampo Division, Teikoku Seiyaku Co., Ltd., Tokushima, Japan.
Ogihara
Y
Y
Takeda
T
T
D000962:Antimalarials / Q000737:chemistry; D002851:Chromatography, High Pressure Liquid / Q000379:methods; D007887:Fabaceae / Q000737:chemistry*; D008519:Medicine, Traditional; D008800:Mexico; D015394:Molecular Structure; D008517:Phytotherapy; D010936:Plant Extracts / Q000737:chemistry; D010946:Plants, Medicinal; D012503:Saponins / Q000737:chemistry* / Q000302:isolation & purification; D016339:Spectrometry, Mass, Fast Atom Bombardment / Q000379:methods; D014315:Triterpenes / Q000737:chemistry* / Q000302:isolation & purification
D000962:Antimalarials; D010936:Plant Extracts; D012503:Saponins; D014315:Triterpenes