title: Synthesis of 5'-deoxy-5'-substituted pyrimidine nucleosides employing intramolecular glycosylation.
abstract: 5'-Deoxy-5'-arylthio and 5'-azido pyrimidine nucleosides were synthesized employing intramolecular glycosylation, in which a reaction intermediate was treated in situ with thiol and an azide salt, respectively.
authors.affiliation: Noguchi Institute, Tokyo, Japan.
authors.forename: H
authors.initials: H
authors.lastname: Sugimura
authors.forename: Y
authors.initials: Y
authors.lastname: Kato
mesh_terms: D001386:Azides; D003853:Deoxyribonucleosides / Q000138:chemical synthesis* / Q000737:chemistry; D006031:Glycosylation; D007202:Indicators and Reagents; D015394:Molecular Structure; D011741:Pyrimidine Nucleosides / Q000138:chemical synthesis* / Q000737:chemistry; D013438:Sulfhydryl Compounds; D013872:Thionucleosides / Q000138:chemical synthesis / Q000737:chemistry
chemical_list: D001386:Azides; D003853:Deoxyribonucleosides; D007202:Indicators and Reagents; D011741:Pyrimidine Nucleosides; D013438:Sulfhydryl Compounds; D013872:Thionucleosides