Force-detected magnetic resonance without field gradients.
A novel method of nuclear magnetic resonance (NMR) is described which promises to be preferable to known general methods at sample length scales below approximately 100 microm. Its advantages stem from the seemingly paradoxical combination of a homogeneous static magnetic field and detection of a mechanical force between a spin-bearing sample and a magnet assembly. In contrast to other methods of force-detected nuclear magnetic resonance (FDNMR), the method is characterized by better observation of magnetization, enhanced resolution, and no gradient (BOOMERANG), and it is generally applicable with respect to sample composition, pulse sequence, and magnetic field strength. Further advantages of portability and low cost stem from the small instrument volume and mass and promise to extend the use of NMR to new applications and environments. A sensitivity analysis, relevant to spectroscopy or imaging, quantifies the advantage of BOOMERANG relative to magnetic induction using microcoils and to FDNMR methods that rely on large gradients of the magnetic field at the sample.
Leskowitz
G M
GM
A.A. Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena 91125, USA.
Madsen
L A
LA
Weitekamp
D P
DP
D009682:Magnetic Resonance Spectroscopy / Q000295:instrumentation / Q000379:methods*; D008280:Magnetics; D019563:Mechanics; D008962:Models, Theoretical; D012680:Sensitivity and Specificity