Dynamically Modified Torsional Eigenstates for Single-Top Molecules.
We present a semiclassical treatment for the inclusion of kinetic energy-dependent variations in the moment of inertia for certain molecules exhibiting internal rotational motion. The model is applied to trifluoroacetyl bromide and the resulting dynamically modified transition energies yield an improved spectral deviation in contrast to the rigid model. Copyright 1998 Academic Press.
Mellor
WE
Faculty of Science and Technology, La Trobe University, Bundoora, Victoria, 3083, Australia
Lee
AR
Kalotas
TM