[A method for knowing the statistical reliability of instrumental measurements].
The precision of instrumental measurements, usually expressed by SD (standard deviation) or RSD (relative standard deviation) is of importance in a society as well as in a world of analytical chemistry. For example, the detection limit and confidence intervals of calibration lines which are based on the precision are inevitable for regulatory science. As is well-known in statistics, however, a small number of repetitive experiments (e.g., 5) lead to a poor reliability of the precision. This presentation shows a method (called FUMI theory) which can provide a precision from a single measurement of noise and signal without any repetitive measurements. The statistical reliability of the precision from the FUMI theory corresponds to that from the repetitive method of 50 experiments.
Hayashi
Y
Y
fumi@nihs.go.jp
Matsuda
R
R
D013223:Statistics as Topic; D014894:Weights and Measures / Q000592:standards*