Synthesis and Characterization of A New Blue-Light-Emitting Polyimide.
5,5'-Bis(4-aminophenyl)-2,2'-bifuryl (PFDA) with a well-defined conjugation length was synthesized, and its soluble poly(amic acid) was prepared by polycondensation with pyromellitic dianhydride (PMDA). The PMDA-PFDA polyimide films were obtained from the poly(amic acid) solution through a conventional spin-casting, baking, and thermal imidization process. The PFDA monomer exhibits intense blue photoluminescence with a maximum at 442 nm in a high quantum yield of 0.92, whereas its polyimide film also emits intense blue photoluminescence with double peak maxima at 419 and 436 nm. The polyimide is insoluble in common organic solvents and thermally stable up to 370 degreesC. Overall, the PMDA-PFDA polyimide can be considered to be a potential candidate material for fabricating optoelectronic devices that emit blue light.
Pyo
SM
Department of Chemistry, Chungnam National University, 220 Gung-dong, Yusung-gu, Taejon 305-764, Korea.
Kim
SI
Shin
TJ
Park
HK
Ree
M
Park
KH
Kang
JS