Physicochemical properties of calcium phosphate coatings produced by pulsed laser deposition at different water vapour pressures.
Calcium phosphate coatings were produced by pulsed laser deposition from targets of non-stoichiometric hydroxyapatite (Ca/P = 1.70) at a substrate temperature of 485 degrees C and different processing pressures of water vapour: 0.15, 0.30, 0.45, 0.60 and 0.80 mbar. The physicochemical properties of these coatings were studied using Fourier-transform IR spectroscopy (FT-IR) and energy dispersive X-ray analysis (EDX). A minimum pressure of water vapour was necessary in order to obtain a crystalline coating, as deduced from the FT-IR spectroscopy of these coatings. This analysis also revealed that when the deposition pressure of water vapour was further increased, the coatings were less crystalline and the content of hydroxyl groups, the carbonate substitution for phosphate, and the Ca/P ratio, as measured by EDX, were lower. These effects can be explained by a combined substitution of carbonate and HPO4(2-) for phosphate, being predominant the carbonate substitution at low pressures and the HPO4(2-) substitution at high pressures.
Arias
J L
JL
Departamento de Física Aplicada, Universidade de Vigo, Spain.
García-Sanz
F J
FJ
Mayor
M B
MB
Chiussi
S
S
Pou
J
J
León
B
B
Pérez-Amor
M
M
D002130:Calcium Phosphates / Q000737:chemistry*; D004577:Electron Probe Microanalysis; D006882:Hydroxyapatites / Q000737:chemistry*; D007834:Lasers; D011312:Pressure; D017550:Spectroscopy, Fourier Transform Infrared; D014835:Volatilization; D014867:Water
D002130:Calcium Phosphates; D006882:Hydroxyapatites; C485828:alpha-tricalcium phosphate; C485830:tetracalcium phosphate; D014867:Water; C485838:calcium phosphate, monobasic, anhydrous; C020243:calcium phosphate; C485829:calcium phosphate, dibasic, anhydrous