Structural determination of the O-deacetylated O-chain of lipopolysaccharide from Burkholderia (Pseudomonas) cepacia strain PVFi-5A.
On the basis of chemical degradation methods and one-and two-dimensional 1H and 13C NMR experiments the novel following structure was established for the O-deacetylated repeating unit of the O-chain of the main Burkholderia (Pseudomonas) cepacia (strain PVFi-5A) lipopolysaccharide: -->4)-beta-D-GalpNAc-(1-->3)-alpha-D-Galp-(1-->6)-alpha-D-GlcpNAc-(1-->.
Cimino
P
P
Dipartimento di Chimica Organica e Biologica, Universitá di Napoli Federico II, Italy.
Corsaro
M M
MM
De Castro
C
C
Evidente
A
A
Marciano
C E
CE
Parrilli
M
M
Sfalanga
A
A
Surico
G
G
D016956:Burkholderia cepacia / Q000737:chemistry* / Q000302:isolation & purification; D002240:Carbohydrate Sequence; D008070:Lipopolysaccharides / Q000737:chemistry* / Q000302:isolation & purification; D018551:Solanum lycopersicum / Q000382:microbiology; D008969:Molecular Sequence Data; D019906:Nuclear Magnetic Resonance, Biomolecular
D008070:Lipopolysaccharides