Monomethacrylate co-monomers for dental resins.
Polymerisation shrinkage is widely recognised as a major drawback of resin based dental restoratives. Bis-GMA is often employed as the principal dimethacrylate monomer. Due to its high viscosity, Bis-GMA is normally mixed with large proportions of low viscosity glycol dimethacrylates. The purpose of this study was to determine whether the polymerisation shrinkage of Bis-GMA-based resins would be lower if alternative monomethacrylate co-monomers were used in place of conventional dimethacrylate co-monomers as viscosity modifiers. Conventional resins used were ethyleneglycol dimethacrylate and triethyleneglycol dimethacrylate; the alternative monofunctional co-monomers were tetrahydrofurfuryl methacrylate, hydroxypropyl methacrylate and isobornyl methacrylate. Model resins containing 54% mol/mol of co-monomer in Bis-GMA and 1% w/w of benzoyl peroxide as initiator were heat-cured at 70 degrees C for 8 h. Polymerisation shrinkage, degree of conversion and concentration of remaining methacrylate groups were calculated from density changes obtained gravimetrically. Other properties evaluated were Young's modulus, water uptake and viscosity of the monomer mixtures. The Bis-GMA-based resins exhibited lower shrinkage when mixed using the monomethacrylates rather than with conventional glycol dimethacrylates. Among the alternative co-monomers, tetrahydrofurfuryl methacrylate conferred the best balance of all measured properties.
Labella
R
R
Department of Operative Dentistry and Dental Materials - School of Dentistry, Oral Pathology and Maxillo-Facial Surgery, Catholic University of Leuven, Belgium. roberto.labella@med.kuleuven.ac.be
Davy
K W
KW
Lambrechts
P
P
Van Meerbeek
B
B
Vanherle
G
G
D000042:Absorption; D000704:Analysis of Variance; D001585:Benzoyl Peroxide / Q000737:chemistry; D017438:Bisphenol A-Glycidyl Methacrylate / Q000737:chemistry*; D003188:Composite Resins; D003432:Cross-Linking Reagents / Q000737:chemistry; D003764:Dental Materials / Q000737:chemistry*; D004548:Elasticity; D006358:Hot Temperature; D006801:Humans; D008422:Materials Testing; D008689:Methacrylates / Q000737:chemistry*; D011092:Polyethylene Glycols / Q000737:chemistry; D011108:Polymers / Q000737:chemistry; D011109:Polymethacrylic Acids / Q000737:chemistry; D013499:Surface Properties; D014783:Viscosity; D014867:Water / Q000737:chemistry
D003188:Composite Resins; D003432:Cross-Linking Reagents; D003764:Dental Materials; D008689:Methacrylates; D011108:Polymers; D011109:Polymethacrylic Acids; D014867:Water; C092890:tetrahydrofurfuryl methacrylate; C020946:triethylene glycol dimethacrylate; D011092:Polyethylene Glycols; D017438:Bisphenol A-Glycidyl Methacrylate; C004919:ethylene dimethacrylate; C032802:hydroxypropyl methacrylate; D001585:Benzoyl Peroxide