Fullerene lipids: synthesis of dialkyl 1,2-[6,6]-methano-[60]-fullerene dicarboxylate derivatives.
Reaction of C60 fullerene with dialkyl bromomalonate (where the alkyl groups consist of short-, medium-, and long-saturated chains or unsaturated long chains) in the presence of sodium hydride gives [6,6]-bridged mono-adducts of methanofullerene. The spectroscopic properties of such fullerenoid lipids are reported.
Jie
M S
MS
Department of Chemistry, The University of Hong Kong, Hong Kong. hrsclkj@hkucc.hku.hk
Cheung
S W
SW
D002244:Carbon / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D037741:Fullerenes; D008956:Models, Chemical
D002264:Carboxylic Acids; D037741:Fullerenes; D002244:Carbon; C069837:fullerene C60