title: Trans-cis amide bond isomerization in fulleroprolines.
abstract: The 1H NMR study of fulleroproline derivative Ac-Fpr-OtBu and its Pro analogue Ac-L-Pro-OtBu over a range of temperatures in toluene-d8 solution has enabled the comparison of their equilibrium and activation parameters for the trans/cis interconversion around the amide partial double bond.
authors.affiliation: Centro Meccanismi di Reazioni Organiche, CNR, Dipartimento di Chimica Organica, Università di Padova, Italy.
authors.forename: A
authors.initials: A
authors.lastname: Bianco
authors.forename: V
authors.initials: V
authors.lastname: Lucchini
authors.forename: M
authors.initials: M
authors.lastname: Maggini
authors.forename: M
authors.initials: M
authors.lastname: Prato
authors.forename: G
authors.initials: G
authors.lastname: Scorrano
authors.forename: C
authors.initials: C
authors.lastname: Toniolo
mesh_terms: D001426:Bacterial Proteins; D002352:Carrier Proteins / Q000737:chemistry*; D047908:Intracellular Signaling Peptides and Proteins; D007536:Isomerism; D009682:Magnetic Resonance Spectroscopy
chemical_list: D001426:Bacterial Proteins; D002352:Carrier Proteins; D047908:Intracellular Signaling Peptides and Proteins; C028640:fructose-induced HPr-like protein, bacteria