Trans-cis amide bond isomerization in fulleroprolines.
The 1H NMR study of fulleroproline derivative Ac-Fpr-OtBu and its Pro analogue Ac-L-Pro-OtBu over a range of temperatures in toluene-d8 solution has enabled the comparison of their equilibrium and activation parameters for the trans/cis interconversion around the amide partial double bond.
Bianco
A
A
Centro Meccanismi di Reazioni Organiche, CNR, Dipartimento di Chimica Organica, Università di Padova, Italy.
Lucchini
V
V
Maggini
M
M
Prato
M
M
Scorrano
G
G
Toniolo
C
C
D001426:Bacterial Proteins; D002352:Carrier Proteins / Q000737:chemistry*; D047908:Intracellular Signaling Peptides and Proteins; D007536:Isomerism; D009682:Magnetic Resonance Spectroscopy
D001426:Bacterial Proteins; D002352:Carrier Proteins; D047908:Intracellular Signaling Peptides and Proteins; C028640:fructose-induced HPr-like protein, bacteria