High-Resolution FTIR Spectrum of the nu5 Band of HCOOD.
The high-resolution Fourier transform infrared spectrum of HCOOD has been measured in the nu5 region between 1120 and 1220 cm-1 with a resolution of 0.004 cm-1. As expected for an in-plane vibrational fundamental mode, the nu5 band is a hybrid band consisting of both a-type and b-type transitions. Using the Watson's A-reduced Hamiltonian in the Ir representation, 1943 infrared transitions have been assigned and fitted to give 12 rovibrational constants for the v5 = 1 state. The nu5 band is primarily A type with a band center at 1177.09378 +/- 0.00002 cm-1. It is found that nu5 is slightly perturbed by the nearby 2nu7. About 90 perturbed transitions were identified. Copyright 1998 Academic Press.
Goh
KL
Faculty of Science, National University of Singapore, Lower Kent Ridge Road, 119260, Singapore
Ong
PP
Tan
TL
Teo
HH
Wang
WF