Capillary electrophoresis and capillary electrophoresis-electrospray-mass spectroscopy for the analysis of heterocyclic amines.
Fourteen heterocyclic amines (HAs) were analyzed by capillary electrophoresis (CE) on a polyvinyl alcohol (PVA)-coated capillary column. The optimized electrolyte is composed of 20 mM ammonium acetate, pH 3.0, and 20% methanol. Similar conditions were applied in electrospray-mass spectrometry (CE-ES-MS). The CE-ES-MS optimization procedure includes the position of the capillary in the stainless steel interface, the flow of the sheath liquid and its composition.
Zhao
Y
Y
Department of Organic Chemistry, University of Ghent, Belgium.
Schelfaut
M
M
Sandra
P
P
Banks
F
F
D000085:Acetates; D019075:Electrophoresis, Capillary / Q000379:methods*; D006571:Heterocyclic Compounds / Q000032:analysis*; D013058:Mass Spectrometry / Q000379:methods*; D000432:Methanol; D011142:Polyvinyl Alcohol
D000085:Acetates; D006571:Heterocyclic Compounds; D011142:Polyvinyl Alcohol; C018824:ammonium acetate; D000432:Methanol