Circular Dichroism at Microwave Frequencies: Calculated Rotational Strengths for Transitions Up to J = 10 for Some Oxirane Derivatives.
Calculated dipole strengths and rotational strengths for microwave transitions in the range of 3-26 GHz are presented for six chiral small molecules. The molecules are the three chiral deuterated oxiranes, methyloxirane, trans-dimethyloxirane, and methylthiirane. Transitions which appear to be the best candidates for observation of circular dichroism in the microwave are identified. Copyright 1998 Academic Press.
Salzman
WR
Department of Chemistry, University of Arizona, Tucson, Arizona, 85721