[On the constituents of the root of fukuchiyama-jio, the hybrid of Rehmannia glutinosa var. purpurea and R. glutinosa forma hueichingensis].
In order to characterize the pharmaceutical utility of the root of Fukuchiyama-jio, which was produced as the hybrid of Rehmannia glutinosa LIBOSCH. var. purpurea MAKINO (Akaya-jio in Japanese) and Rehmannia glutinosa LIBOSCH. forma hueichingensis HSIAO (Kaikei-jio in Japanese) (Scrophulariaceae), we have investigated the chemical constituents of the root of Fukuchiyama-jio in detail in comparison with those of Akaya-jio and Kaikei-jio. Chemical analysis as well as quantitative one by means of gas liquid chromatography (GLC) have shown that the root of Fukuchiyama-jio contains a larger amount of iridoid glucosides as compared with Akaya-jio and Kaikei-jio. During these chemical analyses, a new ionone glucoside named oxyrehmaionoside B (7) along with melasmoside (6) were isolated as the characteristic constituents of Fukuchiyama-jio and the structure of 7 has been determined.
Kitagawa
I
I
Faculty of Pharmaceutical Sciences, Osaka University, Japan.
Hori
K
K
Kawanishi
T
T
Kobayashi
M
M
Kawanishi
F
F
D002849:Chromatography, Gas; D005960:Glucosides / Q000032:analysis* / Q000737:chemistry / Q000302:isolation & purification; D006824:Hybridization, Genetic; D039823:Iridoids; D008968:Molecular Conformation; D010946:Plants, Medicinal / Q000737:chemistry*; D011714:Pyrans / Q000032:analysis* / Q000737:chemistry / Q000302:isolation & purification
D005960:Glucosides; D039823:Iridoids; D011714:Pyrans