title: 95Mo NMR: hyperfine interactions in MoO3, MoS2, MoSe2 Mo3Se4, MoSi2 and Mo2C.
abstract: Nuclear hyperfine interactions have been obtained by nuclear magnetic resonance (NMR) for 95Mo in a number of binary Mo compounds, both insulators and metals, which illustrate the interplay between nuclear quadrupole and chemical (Knight) shift terms. The insulating phases are characterised by nuclear spin lattice relaxation times greater than 100 s, demonstrating the ineffectiveness of indirect phonon Raman relaxation for these compounds.
authors.affiliation: Division of Materials Science and Technology, CSIRO, Clayton, Victoria, Australia. bastow@mst.csiro.au
authors.forename: T J
authors.initials: TJ
authors.lastname: Bastow
mesh_terms: D007554:Isotopes; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D008982:Molybdenum / Q000737:chemistry; D010087:Oxides / Q000737:chemistry
chemical_list: D007554:Isotopes; D010087:Oxides; C082290:molybdenum trioxide; D008982:Molybdenum; C024687:sodium molybdate(VI)