A triterpenoid saponin from Cucumaria frondosa.
The structure of a new triterpenoid saponin, frondoside D, isolated from Cucumaria frondosa has been determined principally by high field 1D and 2D NMR and FAB-MS spectrometry. Frondoside D was shown to be 3 beta-[3-O-methyl-O-beta-D-glucopyranosyl-(1-3)-O-beta-D- xylopyranosyl-(1-4)-[O-beta-D-xylopyranosyl-(1-2)]-O-beta-D- quinovopyranosyl-(1-2)-O-beta-D-4-sulfonatoxylo-pyranosyl]-1 6 beta-acetoxy-23S-hydroxy-holost-7-ene, sodium salt.
Yayli
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N
Department of Chemistry, Karadeniz Technical University, Trabzon, Turkey.
Findlay
J A
JA
D000818:Animals; D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008969:Molecular Sequence Data; D015394:Molecular Structure; D012503:Saponins / Q000737:chemistry* / Q000302:isolation & purification; D012616:Sea Cucumbers / Q000737:chemistry*; D016339:Spectrometry, Mass, Fast Atom Bombardment; D014315:Triterpenes / Q000737:chemistry* / Q000302:isolation & purification
D012503:Saponins; D014315:Triterpenes